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Classify the following transformations according to the reaction type.


In this reaction, substitution takes place, followed by a rearrangment of atoms and groups of atoms.

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Why carbanions are very negative? Discuss the structure of carbanion.


Their reactivity is due to the fact that the negatively charged carbon in them has got a lone pair of electrons. It has a strong tendency to donate this pair to some electron deficient species.
Therefore, carbanion possesses one unshared pair of electrons and three pairs of covalent bonding electrons around the central carbon atom having a negative charge. Thus carbon is sp3 hybridised and shape of the simple carbanion appears to be pyramidal. Due to the presence of nonbonding electrons pair, the bond angle is reduced to a value slightly lesser than the tetrahedral value of 109.5°.



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Give the hybridisation state of each carbon in the following species:
left parenthesis straight i right parenthesis space CH subscript 3 space minus space straight C with bar on top straight H subscript 2 space space space space space space left parenthesis ii right parenthesis space CH subscript 3 space minus space straight C with plus on top straight H subscript 2 space space space space left parenthesis iii right parenthesis space CH subscript 3 CH subscript 2


The hybridisation of the given compound :

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Give reasons why the following two structures I and II cannot be the major contributors to the real structure of CH3COOCH3:


The two structures are less important contributors as they contain charge separation. Also, the structure I contain a carbon atom with an incomplete octet.

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Give two methods for the generation of carbocation. Describe its structure. 


(i) Direct ionisation: The carbon-halogen bond (C-X) in many organic halides generates carbocations in the presence of a highly polar medium.



(ii) Protonation of alkene:



The structure of carbocation: The positively charged carbon of the carbocation is sp2 state of hybridisation. The three sp2 hybridised orbitals which lie in the same plane are involved in the formation of three bonds with other atoms. The unhybridised p-orbital remains vacant. Thus, the carbocation has a flat structure. 


The bond angle around the positively charged carbon is nearly 120° each.

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