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 Multiple Choice QuestionsMultiple Choice Questions

1.

The number of unpaired electrons in[NiCl4]2-, Ni(CO)4 and (Cu(NH3)4]2+ respectively are

  • 0, 2, 1

  • 2, 0, 1

  • 0, 2, 1

  • 2, 2, 0


2.

The pair having the same magnetic moment is:

[At. No. : Cr=24, Mn=25, Fe=26, Co=27]

  • [Cr(H2O)6 ]2+ and [Fe(H2O)6 ]2+

  • [Mn(H2O)6 ]2+ and [Cr(H2O)6 ]2+

  • [CoCl4 ]2− and [Fe(H2O)6 ]2+

  • [CoCl4 ]2− and [Fe(H2O)6 ]2+

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3.

Which one of the following complexes shows optical isomerism?

  • cis[Co(en)2Cl2]Cl

  • trans[Co(en)2Cl2]Cl

  • [Co(NH3)4Cl2 ]Cl

  • [Co(NH3)4Cl2 ]Cl

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4.

The number of geometric isomers that can exist for square planar [Pt (Cl) (py) (NH3) (NH2OH)]+ is (py = pyridine)

  • 2

  • 3

  • 4

  • 4

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5.

The Colour of KMnO4 is due to 

  • M → L charge transfer transition

  • d-d transition

  • L →M charge transfer transition

  • L →M charge transfer transition

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6.

Which of the following compounds will exhibit geometrical isomerism?

  • 1-phenyl-2-butene

  • 3-phenyl-1-butene

  • 2-phenyl-1-butene

  • 2-phenyl-1-butene


A.

1-phenyl-2-butene

Alkene in which different groups are attached with the double bonded carbon atoms, exhibit geometrical isomerism.

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7.

Which of the following compounds is not coloured yellow?

  • Zn2[Fe(CN)6]

  • K3[Co(NO2)6]

  • (NH4)3[As(Mo3O10)4]

  • (NH4)3[As(Mo3O10)4]

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8.

The octahedral complex of a metal ion M3+ with four Monodentate Ligands, L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue respectively. The increasing order of ligand strength of the four ligands is

  • L4< L3<L2<L1

  • L1<L3<L2<L4

  • L3<L2<L4<L1

  • L3<L2<L4<L1

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9.

Which of the following properties are not shown by NO?

  • It is diamagnetic in gaseous state

  • It is a neutral oxide

  • It combines with oxygen to form nitrogen dioxide

  • It combines with oxygen to form nitrogen dioxide

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10.

Which of the following complex species is not expected to exhibit optical isomerism? 

  • [Co(en)3]3+

  • [Co(en)2Cl2]+

  • [Co(NH3)3Cl3]

  • [Co(NH3)3Cl3]

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