In which of the following reactions carbon-carbon bond formation takes place ?
Cannizaro
Reimer - Tiemann
HVZ reaction
Schmidt reaction
Which gives only mono - substituted product ?
o - dinitrobenzene
m - dinitrobenzene
p - dinitrobenzene
Nitrobenzene
Order of boiling point is :
HF > HI > HBr > HCl
HF > HBr > HI > HCl
HCl > HBr > HI > HF
HCl > HI > HBr > HF
A.
HF > HI > HBr > HCl
Boiling point of hydrogen halides increase with increasing molecular mass because van der Waals' force of attraction increase with rise in molecular weight .Hydrogen fluoride (HF) has abnormally high boiling point due to their existence as a polymeric compound by forming inter-molecular hydr-ogen bonding .
Thus decreasing order of boiling point is
> HI > HBr >
If the enolate ion combines with carbonyl group of ester , we get :
aldol
, - unsaturated ester
- keto aldehyde
acid
Which of the following compounds will react with NaHCO3 solution to give sodium salt and carbon dioxide ?
Acetic acid
n - hexanol
Phenol
Both (b) and (c)