The function of anhydrous AlCl3 in the Friedel-Craft's reaction is to :
absorb water
absorb HCl
to produce electrophile
to produce nucleophile
C.
to produce electrophile
The function of anhydrous AlCl3 in the Friedel-Craft's reaction is to produce electrophile , eg , in case of Friedel Craft's alkylation reaction ,it produces electrophile as :
CH3-Cl + AlCl3
The linear molecule is :
CH3
C2H2
NH3
H2O
B.
C2H2
Molecule | Hybridisation | Geometry |
CH4 | sp3 | Tetrahedral |
C2H2 | sp | Linear |
NH3 | sp3 | Pyramidal (due to 1 Ip) |
H2O | sp3 | V-shaped (due to 2 lp) |
When two double bonds are present on adjacent carbon atoms , the diene is called as :
conjugated diene
cumulative diene
isolated diene
None of these
B.
cumulative diene
When two double bonds are present on adjacent carbon atoms , the diene is called cumulative diene .Allene (C3H4) is the simplest example of cumulative diene .
H2C=C=CH2 (allene)
B RCCR A ,
A and B are geometrical isomers (RCH=CHR)
A is cis , B is trans
A is trans , B is cis
A and B both are cis
A and B both are trans
B.
A is trans , B is cis
An element with atomic number 84 and mass number 218 loses one a-particle and two -particles in three successive stages .The resulting element will have :
at. no. 84 and mass no. 214
at no. 82 and mass no. 214
at. no. 84 and mass no. 218
at. no. 82 and mass no. 218
A.
at. no. 84 and mass no. 214
Let element is 'A'
84A218 82B214 83C214 84D214
Hence , the resulting element (D) will have at. no. 84 and mass no. 214 .
The homologue of ethyne is :
C2H4
C3H6
C3H3
C3H4
D.
C3H4
The successive members of a homologous series differ by a-CH2 group or by 12 + 2 x 1 = 14 mass unit .
Hence , the homologue of HCCH (ethyne , C2H2) is CH3-CCH (propyne , C3H4) .
Calcium burns in nitrogen to produce a white powder which dissolves in sufficient water to produce a gas A and an alkaline solution .The solution on exposure to air produces a thin solid layer of B on the surface .The compounds A and B will be :
Ca3N2 , NH3
NH3 , CO2
Ca(OH)2 , CaCO3
NH3 , CaCO3
D.
NH3 , CaCO3
A = NH3 and B = CaCO3
The reactions are as follows
3CaN2 + N2
Ca3N2 + 6H2O 3Ca(OH)2 + 2NH3 (A)
Ca(OH)2 +
Consider the reaction ,
Fe2+ Fe3+ + e-
the reaction towards the left is a reduction
the reduction towards the right is a reduction
the reaction towards the right is an oxidation
the reaction towards the right is an oxidation and the reaction towards the left is an reduction
D.
the reaction towards the right is an oxidation and the reaction towards the left is an reduction
Fe2+ Fe3+ + e-
The reaction towards the right is an oxidation reaction because Fe2+ ion loose one electron and changes into Fe3+ ion .The reaction towards the left is an reduction reaction because Fe3+ ion gain one electron and changes into Fe2+ ion .
Structure of (SiO4)4- ion is :
tetrahedral
square planar
octahedral
planar triangular
A.
tetrahedral
(SiO4)4- ions are the basic structural units of silicates and arranged tetrahedrally .
discrete SiO44- tetrahedron
An organic substance containing carbon , hydrogen and oxygen gave the following percentage composition .
C = 40.687 % , H = 5.085% and O = 54.228 %
What is the empirical formula of the compound ?
CH3O
C2H2O
CH4O
C2H3O2
D.
C2H3O2
Symbol | Percentage | Relative no. of moles |
Simplest molar ratio |
Simplest whole no. molar ratio |
C | 40.687 | = 3.390 | = 1 | 2 |
H | 5.085 | = 5.085 | = 1.5 | 3 |
O | 54.228 | = 3.389 | = 1 | 2 |