Explain the relationship between the rate of production of iodine and rate of disappearance of hydrogen iodide in the following reaction?
        2HI   H2+I2.

Rate of disappearance of HI

                              = -dHIdt

Rate of appearance of I2 = dI2dt.

From the chemical equation,
Rate of production I2

                = 12×Rate of disappearance of HI

Therefore, dI2dt = 12 dHIdt.

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Express the relationship between the rate of production of water and the rate of disappearance of oxygen in the following reaction:
                       2H2+O2    2H2O

Rate of production of water

                      = 12×dH2Odt
Rate of disappearance of oxygen

                     =-dO2dt
                 =-dO2dt = 12×dH2Odt.

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Express the relationship between the rate of production of NOCl and the rate of disappearance of chlorine in the following reaction:

2NO+Cl2   2NOCl.

Rate of production of NOCl

=dNOCldt
Rate of disappearance of Cl2

=-dCl2dt

From the chemical equation, Rate of disappearance of Cl
2

                      = 12×Rate of formation of NOCl
    dCl2dt = 12dNOCldt.
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Explain the relationship between the rate of production of oxygen and the rate of disappearance of hydrogen peroxide (H2O2) in the following reaction:
                        2H2O2    2H2O + O2

The relationship between the rate of production of oxygen and the rate of disappearance of hydrogen peroxide.

dO2dt = 12×-dH2O2dt.
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Starting with differential rate law equation for a first order reaction, derive the integrated rate law equation for a first order reaction. How is it related to the rate constant?


The rate of the reaction is proportional to the
first power of the concentration of the reactant R. For example,

R → P


-dAdt=kA    or     -dAA = k dt

On integrating, we get

                  -dAA = kdt


or          -In A = kt + C ..........1

Again, C is the constant of integration and its value can be determined
easily.

When t = 0, A = [A]0, where [A]0 is the initial concentration of the reactant.
Therefore,above  equation can be written as
ln [A]0 = –k × 0 + C
ln [A]0 = C
putting the value of C in equation (1), we get

or            - In A = kt - In A0

           In A0A = kt   or

taking antilog both side, we get 

    A=A0     e-kt


   (Units of K are s-1).

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