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Chemical Kinetics
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Chemistry I
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Chemistry
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Chemical Kinetics
When the rate of the reaction becomes equal to the specific reaction rate?
When the concentrations of all the reactants are taken as unity.
Rate = k[A] [B]
where [A] = [B] = 1 mol L
–1
, then rate = k.
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What is the shape between log k vs. 1/ T? What is the relationship between its slope and activation energy (Ea) ?
It is a straight line whose slope
=
-
E
o
2
.
303
R
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Out of the zero, first and second order reactions which has the same units for rate of the reaction and rate constant.
Zero order. The unit for rate as well as rate constant is mol L
–1
sec
–1
.
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State two factors which affect the rate of a chemical reaction.
Following are the factor that effect the rate of chemical reaction:
i) Temperature of the rection
ii) The concentration of the reactants.
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The following graph is a plot of t
1/2
and concentration. What is the order of the reaction?
The order of the reaction is zero, as t
1/2
is independent of the concentration of the reactant.
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