State the ‘rate law’ for the chemical reactions.

 It is the expression, which shows how the reaction rate is related to concentration

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Wha t is meant by order of a reaction being zero?

In some reactions, the rate is apparently independent of the reactant concentration. The rates of these zero-order reactions do not vary with increasing nor decreasing reactants concentrations. This means that the rate of thereaction is equal to the rate constant, k , of that reaction.

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Is there any reaction for which reaction rate does not decrease with time?


Reaction that are auto catalytic can have their rate increase with time i.e. as the product is formes the product start to work as catalyst and increase the reaction.

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For the reaction Cl2(g) + 2NO(g) → 2NOCl(g) the rate law is expressed as rate = k[Cl2] [NO]2.
What is the overall order of reaction?

The overall order of the reaction for given 
rate = k[Cl2] [NO]2


order of Cl= 1
order of [NO]2 =2

order =1+2 =3
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Express the rate of the following reaction in terms of disappearance of hydrogen in the reaction.
3H2(g) + N2(g) → 2NH3(g)

-13d[H2]t =-d[N2]t =12d[NH3]t

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