The heat is liberated when 1.89 g of benzoic acid is burnt in a bomb calorimeter at 25 °C and it increases the temperature of 18.94 kg of water by 0.632 °C. If the specific heat of water at 25 °C is 0.998 cal/g-deg, then value of the heat of combustion of benzoic acid is
881.1 kcal
981.1 kcal
771.1 kcal
871.2 kcal
C.
771.1 kcal
Mass of benzoic acid = 1.89 g
Temperature of bomb calorimeter = 25 °C = 298 K
Mass of water (m) = 18.94 kg= 18940 g
Increase in temperature (t) = 0.632 °C
Specific heat of water (s)= 0.998 cal/g-deg
Heat gained by water or heat liberated by benzoic acid ( Q)= mst
= 18940 0.998 0.632 = 11946.14 cal
Since, 1.89 g of acid, liberates 11946.14 cal of heat, therefore heat liberated by 122 g (mol. wt. of benzoic acid) of acid =
= 771126.5 cal 771.1 kcal
Assertion : trans-Pent-2-ene is polar but trans- but-2-ene is non-polar.
Reason : The polarity of cis-isomer is more than trans-isomer, which are either non-polar or less polar.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false
Assertion : The number of tetrahedral voids is double the number of octahedral voids.
Reason : The size of the tetrahedral voids is half of that of the octahedral void.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
Assertion : The second dissociation constant of fumaric acid is greater than maleic acid.
Reason : Higher the dissociation constant of acid, more is the acidic character.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion
If assertion is true but reason is false.
If both assertion and reason are false
Assertion : [Fe(CN)6]3- has d2sp3 type hybridisation.
Reason: [Fe(CN)6]3- ion shows magnetic moment corresponding to two unpaired electrons.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false
If both assertion and reason are false.
Assertion: Both (2px) and *(2px) MO's have one nodal plane.
Reason : All MO's formed by side way overlapping of 2p- orbitals have one nodal plane.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion
If assertion is true but reason is false
If both assertion and reason are false.
Assertion : Spontaneous process is an irreversible process and may be reversed by some external agency.
Reason : Decrease in enthalpy is a contributory factor for spontaneity.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false
If both assertion and reason are false.
H2O is polar, whereas BeF2 is not because
electronegativity of F is greaterthan that of O.
H2O involves H-bonding, whereas BeF2 is a discrete molecule
H2O is angular and BeF2 is linear
H2O is linear and BeF2 is angular.
The correct order of solubility ofthe following compounds in water is
Ba(OH)2 < Mg(OH)2
BaCO3 > CaCO3
Ca(OH)2 Mg(OH)2
CaSO4 < MgSO4
(R)-2-Iodobutane is treated with NaI in acetone and allowed to stand for a long time. The product eventually formed is
(R)-2-iodobutane
(S)-2-iodobutane
(±)-2-iodobutane
(±)-1, 2-diiodobutane