Multiple Choice Questions

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Which of the following biphenyls is optically active?


A.

D.

The biphenyl compounds having a proper substitution at ortho-position of benzene rings result steric hindrance. This steric hindrance makes the biphenyl system non-planar and hence optically active compounds.

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The correct statement regarding a carbonyl compound with a hydrogen atom on its alpha -carbon, is

  • a carbonyl compound with a hydrogen atom on its alpha -carbon rapidly equilibrates with its corresponding enol and this process is known as aldehyde-ketone equilibration.

  • a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as carbonylation

  • a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as keto-enol tautomerism

  • a carbonyl compound with a hydrogen atom on its alpha-carbon rapidly equilibrates with its corresponding enol and this process is known as keto-enol tautomerism

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Natural rubber has

  • All trans-configuration

  • Alternate cis and trans configuration

  • Random cis and trans configuration

  • Random cis and trans configuration

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Which of the following is an analgesic?

  • Penicillin

  • Streptomycin

  • Chloromycetin

  • Chloromycetin

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Which of the following reagents would distinguish cis-cyclopenta-1-,2-diol from the trans isomer?

  • Ozone

  • MnO2

  • Aluminium isopropoxide

  • Aluminium isopropoxide

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For the following reactions,

i) CH3 CH2 CH2Br + KOH --> CH3CH=CH2 +KBr +H2O

ii)  


iii) 

  • (i) is elimination reaction, (ii) is substitution reaction, and (iii) is addition reaction.

  • (i) is elimination reaction, (ii) is addition reaction, (iii) is substitution reactions.

  • (i) is substitution, (ii) addition reaction (iii) is addition reactions

  • (i) is substitution, (ii) addition reaction (iii) is addition reactions

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Which of the following statement is false?

  • Ca2+ ions are important in blood clotting

  • Ca2+ ions are not important in maintaining the regular beating of the heart.

  • Mg2+ ions are important in the green parts of plants

  • Mg2+ ions are important in the green parts of plants

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The reaction


Can be classified as

  • Alcohol formation reaction

  • Dehydration reaction

  • Williamson alcohol synthesis reaction

  • Williamson alcohol synthesis reaction

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The correct statement regarding the basicity of arylamines is

  • Arylamines are generally more basic than alkylamines because the nitrogen lone pair electrons are not delocalized by interaction with the aromatic ring pi-electron system

  • Arylamines are generally more basic than alkylamines, because of aryl group

  • Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hydridized.

  • Arylamines are generally more basic than alkylamines because the nitrogen atom in arylamines is sp-hydridized.

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In a protein molecule various amino acids are linked together by

  • β-glycosidic bond
  • peptide bond

  • dative bond

  • dative bond

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