Describe simple tests for distinguishing:
C6HsNH3 +Cl- and p-ClC6H4NH2


Aqueous silver nitrate precipitates from C6H5NH3+Clbut does not forms with p-ClC6H4NH2.
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Describe simple tests for distinguishing:
(CH3)4N+OH and (CH3)2NCH2OH


CrO3 is reduced to green Cr3+ by (CH3)2NCH2OH.
(CH3)4N+OH- is strongly basic to litmus.
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Describe simple tests for distinguishing:
p-CH3COC6H4NH2 and CH3CONHC6H5


Cold dilute HCl dissolves p-CH3COC6H4 which also gives a positive iodoform test with NaOH.
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Arrange the following in the order of decreasing basicity:
NH3, CH3NH2, C6H5NH2 (C6H5)2NH.


CH3NH2 > NH> C6H5NH2 > (C6H5)2NH > (C6H5)3N.
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Describe simple tests for distinguishing:
CH3ONHC6H5 and C6H5CONH2


With hot aqueous NaOH, only C6H5CONH2 liberates ammonia.
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