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Explain why
(a) The angle of contact of mercury with glass is obtuse, while that of water with glass is acute.


The angle between the tangent to the liquid surface at the point of contact and the surface inside the liquid is called the angle of contact (θ).

At the line of contact, the surface forces between the three media must be in equilibrium.

i.e., cos θ = (Ssa - Sla) / Sla 

where,

sla is the liquid-air interface, 
Ssa is the solid-air interface

The angle of contact θ , is obtuse if Ssa < Sla (as in the case of mercury on glass). This angle is acute if Ssl < Sla (as in the case of water on glass).


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Explain why:
(b) Atmospheric pressure at a height of about 6 km decreases to nearly half of its value at the sea level, though the height of the atmosphere is more than 100 km.


Explain why?
(b) Water on a clean glass surface tends to spread out while mercury on the same surface tends to form drops. (Put differently, water wets glass while mercury does not.)

Expalin why?
(c) Surface tension of a liquid is independent of the area of the surface

Explain why:
(d) Water with detergent dissolved in it should have small angles of contact.

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