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The Solid State

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Classification of Crystalline Solids

Depending upon the nature of bonds, crystalline solids are of four types.

  1. Molecular Solids
  2. Ionic Solids
  3. Covalent Solids
  4. Metallic Solids

Covalent or Network Solids

Property of covalent solids

Constituent particles Major binding force Properties Example
Atoms Covalent bonds Very hard, high melting point, high heat of fusion, insulator Quartz, diamond etc. Exception is graphite

Ionic Solids

Property of ionic solids

Constituent particles Major binding force Properties Example
Positive and negative ions Electrostatic forces of attraction Brittle, high melting point, very higt heat of fusion NaCl, MgO, ZnS, LiF, etc

Metallic Solids

Property of Metallic solids

Constituent particles Major binding force Properties Example
Positive ions and mobile electrons Metallic bonds Very soft to very hard, ductile and malleable, conductors All metals and alloys

Molecular Solids

Property of molecular solids

Constituent particles Major binding force Properties Example
Small molecules Vander Waal's forces Soft, low Melting Point, volatile, Insulators. Solid CO2, wax, Iodine, etc

 

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