The correct order of reactivity of phenyl Magnesium bromide with

Previous Year Papers

Download Solved Question Papers Free for Offline Practice and view Solutions Online.

Test Series

Take Zigya Full and Sectional Test Series. Time it out for real assessment and get your results instantly.

Test Yourself

Practice and master your preparation for a specific topic or chapter. Check you scores at the end of the test.
Advertisement

 Multiple Choice QuestionsMultiple Choice Questions

761.

Hydrolysis of phenyl isocyanide forms

  • benzoic acid

  • formic acid

  • acetic acid

  • None of these


762.

Reaction of ethyl formate with excess of CH3MgI followed by hydrolysis gives

  • n-propyl alcohol

  • isopropyl alcohol

  • acetaldehyde

  • acetone


763.

Which among the following alcohols is most reactive with sodium wire?

  • Ethanol

  • 2-Propanol

  • 2-Butanol

  • 2-Methyl-2-butanol


764.

In Williamson's synthesis, ethoxyethane is prepared by :

  • passing ethanol over heated alumina

  • heating sodium ethoxide with ethyl bromide

  • treating ethyl alcohol with excess of H2SO4 at 430-440 K

  • heating ethanol with dry Ag2O


Advertisement
Advertisement

765.

The correct order of reactivity of phenyl Magnesium bromide with the following compound is:

  • (II)> (III)> (I)

  • (I)> (III)> (II)

  • (II)> (I)> (III)

  • (I)> (II)> (III)


C.

(II)> (I)> (III)

Among aldehyde and a ketone, aldehydes are more electrophilic as in ketones. If charge on carbonyl carbon is decreased by +I effect of both alkyl groups.

Moreover in the tetrahedral intermediate aldehydes have less steric repulsion than ketone and aldehydes increases the--ve charge on oxygen less in comparison to ketmes.

Based on the above the order of reactivity is:

(II) > (I) > (III)


Advertisement
766.

reacts with acetic acid in presence of Hg2+ to give:

  • None of these


767.

Phenol and benzoic acid are distinguished by

  • NaOH

  • NaHCO3

  • Na2CO3

  • H2SO4


768.

Phenol reacts with chloroform in presence of

  • H2SO4

  • KOH

  • NaNO2/ HCl

  • G.R.


Advertisement
769.

The alcohol that produces turbidity immediately with ZnCL2 + conc. HCl at room temperature:

  • 1- hydroxybutane

  • 2- hydroxybutane

  • 2- hydroxy -2- methyl propane

  • 1- hydroxy -2- methyl propane


770.

The compound which reacts faster with Lucas reagent is

  • butan-1-ol

  • butan-2-ol

  • 2-methyl-propan-1-ol

  • 2-methyl propan-2-ol


Advertisement