What will be the product ,when carboxy phenol ,obtained by Reimer Tiemann's process ,is deoxidised with Zn powder ?

The product obtained ,heating ethanol with conc. H₂SO₄ at 165° - 170°C is :

• (C₂H₅)₂SO₄

• CH₂=CH₂

• CH₂F-CH₂F

• CF₂=CFCl

The structural formula of picric acid is :

Phenol reacts with aqueous bromine to give :

• 

• 

•  + 

• 

Assertion : t-Butyl methyl ether is not prepared by the reaction of t-butyl bromide with sodium methoxide.

Reason : Sodium methoxide is a strong nucleophile.

• If both assertion and reason are true and reason is the correct explanation of assertion.

• If both assertion and reason are true but reason is not the correct explanation of assertion.

• If assertion is true but reason is false.

• If both assertion and reason are false.

Among the following the most reactive towards alcoholic KOH is

• CH₂=CHBr

• CH₃COCH₂CH₂Br

• CH₃CH₂Br

• CH₃CH₂CH₂Br

Propan-1-ol can be prepared from propene by

• H₂O/H₂SO₄

• Hg(OAc)₂/H₂O followed by NaBH₄

• B₂H₆ followed by H₂O₂

• CH₃CO₂H/H₂SO₄

Assertion : Molar entropy of vaporisation of water is different from ethanol.

Reason : Water is more polar than ethanol.

• If both assertion and reason are true and reason is the correct explanation of assertion.

• If both assertion and reason are true but reason is not the correct explanation of assertion

• If assertion is true but reason is false

• If both assertion and reason are false.

869.

The product of the given reacion is

• 

• 

• 

• 

In the reaction,

R MgBr + HC(OEt)₃ $\stackrel{\mathrm{Ether}, {\mathrm{H}}_3{\mathrm{O}}^{+}}{\to }$ P, the product P is

• RCHO

• R₂CHOEt

• R₃CH

• RCH(OEt)₂