Explain the reason why:Carboxylic acids, despite the presence of

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 Multiple Choice QuestionsShort Answer Type

361. How will you prepare:

Propyne from propanal? 


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362.

Explain the reason why:
Carbon-oxygen bond lengths in formic acid are 1.23 Å and 1.36 Å, but both the carbon-oxygen bonds in sodium formate have the same value, 1.27 Å.

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363.

Explain the reason why:
Acetic acid can be halogenated in the presence of red P and Cl2 but formic acid cannot be halogenated in the same way.

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364.

Explain the reason why:
Formic acid is stronger than acetic acid.

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365.

Explain the reason why:
The carboxylate ion, RCOO- is more stable than the carboxylic acid, RCOOH.

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366.

Explain the reason why:

Carboxylic acids, despite the presence of C = O group in the molecule, do not form oximes, hydrazones, etc.


The double bond character of the C = O bond in carboxylic acid (and carboxylates) is greatly reduced due to resonance. Thus, carboxylic acid does not form oximes, hydrozones etc.


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 Multiple Choice QuestionsFill In the Blanks

367. Vapour of an organic compound X, when passed over hot reduced copper at 573 K, gave acetone. The formula of X _______.
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368.

When a mixture of acetic acid and formic acid vapour is passed over MnO catalyst at 573 K, _________ is formed.

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369.

When acetaldehyde is treated with aluminium ethoxide, _________ is formed.

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370. When a carboxy compound is heated with conc. HI and red phosphorus, a hydrocarbon is formed. This reaction is known as _________.
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