State whether the following statements are True or False: from

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 Multiple Choice QuestionsTrue Or False

381. State whether the following statements are True or False:

A.

The reaction of methyl magnesium bromide with acetone followed by hydrolysis gives secondary butanol.

B.

The yield of a ketone when a secondary alcohol is oxidised is more than the yield of an aldehyde when a primary alcohol is oxidised.

C.

The addition reactions of carbonyl com-pounds are nucleophilic addition reactions.

D.

The boiling point of propionic acid is less than that of n-butyl alcohol, an alcohol of comparable, molecular mass.

E.

In reactions in which formic acid acts as a reducing agent, it is itself oxidised to carbon monoxide.
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382. State whether the following statements are True or False:

A.

Benzaldehyde undergoes aldol conden-sation in alkaline medium.

B.

Aldol condensation is given by all alde-hydes and ketones.

C.

Ethanoyl chloride on reaction with H2/Pd gives ethanal.

D.

Aldehydes and ketones undergo nucleophilic addition reaction.

E.

Acetaldehyde and propionaldehyde can be distinguished by using an iodoform test.


A. FALSE
B. FALSE
C. FALSE
D. TRUE
E. TRUE
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383. State whether the following statements are True or False:

A.

Benzaldehyde gives Cannizzaro reaction as it does not have any α-hydrogen.

B.

The boiling point of propanoic acid is lesser than that of butano1-1.

C.

Formic acid does not reduce Tollen’s reagent.

D.

All the C—O bond lengths in carboxylate ion are identical. 

E.

Acetate ion is stronger base than methoxide ion.
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 Multiple Choice QuestionsMultiple Choice Questions

384. The formation of cyanohydrin from acetaldehyde is an example of
  • electrophilic addition
  • nucleophilic addition
  • nucleophilic substitution
  • free radical substitution.
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385.

Among the following acids, the strongest one is:

  • formic acid
  • propionic acid
  • butyric acid
  • benzoic acid
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386. Cannizzaro reaction cannot be given by
  • (CH3)3CCHO
  • CH3CHO
  • HCHO
  • C6H5CHO
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387.

The formation of cyanohydrin from a ketone is an example of

  • electrophilic addition
  • nucleophilic addition
  • nucleophilic substitution
  • electrophilic substitution
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388.

When acetaldehyde is heated with Fehling solution, it gives a precipitate of

  • Cu

  • CuO

  • Cu2O
  • Cu + CuO + Cu2O
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389.

The aldol condensations of acetaldehyde results in the formation of

  • CH3·CO·CHOH·CH3
  • CH3·CHOH·CH2 ·CHO
  • CH3·CH2·CHOH ·CHO
  • CH3CH2OH + CH3COOH
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390.

Cannizzaro reaction is not given by

  • trimethyl acetaldehyde
  • acetaldehyde
  • benzaldehyde
  • formaldehyde
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