In the reaction sequence,C2H5Cl  + KCN 

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 Multiple Choice QuestionsMultiple Choice Questions

651.

Which of the following aldehydes give red precipitate with Fehling solution?

  • Benzaldehyde

  • Salicylaldehyde

  • Acetaldehyde

  • None of the above


652.

When acetaldehyde is reacted with LiAlH4, what is the product formed?

  • CH3COOH

  • CH3CH2OH

  • CH3OH

  • HCOOH


653.

Acetic acid is reacted with metallic sodium to form hydrogen and X. When X is heated with sodalime, Y and sodium carbonate are formed. Y is .

  • C2H6

  • CH4

  • CH3COONa

  • CH3CONH2


654.

A HCl (CH3)2C=CHCOCH3, A is

  • acetone

  • propionaldehyde

  • formaldehyde

  • acetaldehyde


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655.

An organic compound X gives a red precipitate on heating with Fehling's solution . Which one of the following reactions yields X as a major product?

  • HCHO (ii) H2O(i)CH3MgI

  • C2H5Br + AgOH 

  • 2C2H5Br + Ag2O 

  • C2H2 + H2O 1% HgSO4 60°C40% H2SO4


656.

In the reaction, C2H5OC2H5 + CO   X.  What is X?

  • Diethyl carbonate

  • Ethyl carbonate

  • Diethyl peroxide

  • Ethyl propionate


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657.

 In the reaction sequence,

C2H5Cl  + KCN C2H5OH X H3O°

What is the molecular formula of Y?

  • C3H6O2

  • C3H5N

  • C2H4O2

  • C2H6O


A.

C3H6O2

C2H5Cl + KCN C2H5OH  C2H5CN X+ KClC2H5CN  H3O+, 2H2O C2H5COOHY or C3H6O2 +NH3

So, the molecular formula of the Y is C3H6O2.


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658.

What is the catalyst used in the conversion of acetaldehyde to acetic acid ?

  • Manganese acetate

  • LiAlH4

  • H2/ NI

  • Na/ NH3


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659.

What is X in the following reaction?

2CH3COCH3 Ba(OH)2 X

  • H3C-C||CH3OH-CH2-C||O-CH3

  • H3C-C||CH3OH-CH2-CH2-CHO

  • CH3CH(CH3)CH2COCH3

  • H3C-CH|CH3-CH|OH-C||O-CH3


660.

The chemicals used for preparing acetophenone are

(A) C6H6

(B) CH3COCH3

(C) CH3COCl

(D) Anhydrous AlCl3

  • A, B, C

  • B, C, D

  • A, C, D

  • A, B, D


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