Which of the following compounds is not formed in iodoform r

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 Multiple Choice QuestionsMultiple Choice Questions

1091.

Which of the following compounds has maximum volatility?


1092.

Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is


1093.

The order of stability of the following tatutomeric compound is

           

  • I> II> III

  • III > II> I

  • II> I> III

  • II > III> I


1094.

The reaction of formaldehyde and ammonia gives:

  • hexamethylene tetramine

  • bakelite

  • urea

  • triethylene tetramine


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1095.

Which of the following compounds is not formed in iodoform reaction of acetone?

  • CH3COCH2I

  • ICH2COCH2I

  • CH3COCHI2

  • CH3COCl3


B.

ICH2COCH2I

Mechanism of iodoform reaction takes place by two steps:

(I) Iodination of -CO-CH3 group to form -CO-Cl3

CH3-CO-CH3 OI- CH3-CO-CH2I + OH-

CH3-CO-CH2OI- CH3-CO-CHI2 + OH-

CH3-CO-CHI2 OI- CH3-CO-CI3 + OH-

(II) Elimination of Cl3 as : CI3- anion


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1096.

Keto - enol tautomerism is not observed in

  • C6H5COC6H5

  • C6H5COCH=CH2

  • C6H5COCH2COCH3

  • CH3COCH2COCH3


1097.

Which one of the following produced when acetone is saturated with HCl gas?

  • Acetone alcohol

  • Phorone

  • Mesityl oxide

  • Benzene


1098.

For making distinction between 2-pentanone and 3-pentanone, the reagent to be employed is

  • K2Cr2O7/H2SO4

  • Zn-Hg/HCl

  • SeO2

  • Iodine/NaOH


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 Multiple Choice QuestionsShort Answer Type

1099.

An organic compound 'A' on treatment with ammoniacal silver nitrate gives metallic silver and produces a yellow crystalline precipitate of molecular formula C9H10N4O4 on treatment with Brady's reagent. Give the structure of the organic compound 'A'.


 Multiple Choice QuestionsMultiple Choice Questions

1100.

Which one of the following gives, on ozonolysis, both aldehydes and ketones?

  • Me2C = CHMe

  • Me2C = CMe2

  • MeCH2 - C(Me) = CMe2

  • MeCH(Me) - CH = CHMe


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