Which one of the following conversions involve change in both hyb

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 Multiple Choice QuestionsMultiple Choice Questions

531.

The number of antibonding electron pairs in O22- molecular ion on the basis of molecular orbital theory is (Atomic number of O is 18)

  • 5

  • 4

  • 3

  • 2


532.

Maximum number of molecules of CH3I that can react with a molecule of CH3NH2 are

  • 3

  • 4

  • 2

  • 1


533.

An octahedral complex is formed when hybrid orbitals of the following type are involved

  • sp3

  • dsp2

  • d2sp3

  • sp2d2


534.

The angle strain in cyclobutane is

  • 24°44'

  • 29°16'

  • 19°22'

  • 9°44'


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535.

The correct statement with regard to H2+ and H2- is

  • both H2+ and H2- are equally stable

  • both H2+ and H2- do not exist

  • H2- is more stable than H2+

  • H2+ is more stable than H2-


536.

Arrange the following in the increasing order of their bond order

O2, O2+ , O2- and O22-

  • O22-, O2-, O2, O2+

  • O22-, O2-, O2+, O2

  • O2+, O2, O2-, O22-

  • O2, O2+, O2-, O22-


537.

Among the following, the compound that contains ionic, covalent and co-ordinate linkage is

  • NH3

  • NH4Cl

  • NaCl

  • CaO


538.

A covalent molecule AB3 has pyramidal structure. The number of lone pair and bond pair of electrons in the molecule are respectively

  • 2 and 2

  • 0 and 4

  • 3 and 1

  • 1 and 3


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539.

The magnetic moment of a transition metal ion is 15 BM. Therefore, the number of unpaired electrons present in it is

  • 3

  • 4

  • 1

  • 2


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540.

Which one of the following conversions involve change in both hybridisation and shape?

  • CH4 → C2H6

  • NH3 → NH4+

  • BF3 → BF4-

  • H2O → H3O+


C.

BF3 → BF4-

(a)      CH4                         CH3-CH3     4bp+ 0lp                         4bp     4bpHybridisation sp3                  sp3       sp3structure tetrahedral           tetrahedral(b)    NH3                       NH4+     3bp+1lp                        4bpHybridisation sp3              sp3Structure pyramidal         tetrahedral(c)  BF3                               BF4-     3bp                                   4bpHybridisation sp2                sp3Structure trigonal planar    tetrahedral(d)  H2O                             H3O+   2bp+2lp                            3bp+1lpHybridisation sp3                   sp3structure angular                   pyramidal

Thus, conversion of BF3 into BF4- involves change in both hybridisation and shape.


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