Important Questions of Organic Chemistry – Some Basic Principles and Techniques Chemistry | Zigya

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311.

Of the five isomeric hexanes, the isomer which can give two monochlorinated compounds is

  • n-hexane

  • 2, 3-dimethylbutane

  • 2,2-dimethylbutane

  • 2,2-dimethylbutane

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312.

An organic compound having molecular mass 60 is found to contain C = 20%, H = 6.67% and N = 46.67% while rest is oxygen. On heating, it gives NH3 along with a solid residue. The solid residue give violet colour with alkaline copper sulphate solution. The compound is

  • CH3NCO

  • CH3CONH2

  • (NH2)2CO

  • (NH2)2CO

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313.

The ammonia evolved from the treatment of 0.30 g of an organic compound for the estimation of nitrogen was passed in 100 mL of 0.1 M sulphuric acid. The excess of acid required 20 mL of 0.5 M sodium hydroxide solution hydroxide solutio for complete neutralization. The organic compound is

  • acetamide

  • thiourea

  • urea

  • urea

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314.

When metal  ‘M’ is treated with NaOH, a white gelatinous precipitate ‘X’ is obtained, which is soluble in excess of NaOH. Compound ‘X’ when heated strongly gives an oxide which is used in chromatography as an adsorbent. The metal ‘M’ is

  • Fe

  • Zn

  • Ca

  • Al


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315.

Which statement is not correct for ortho and para hydrogen?

  • They have different boiling points

  • Ortho-form is more stable than para-form

  • They differ in their nuclear spin

  • The ratio of ortho to para hydrogen changes with change in temperature


316.

In the IUPAC system, PhCH2CH2CO2H is named as

  • 3-phenylpropanoic acid

  • benzylacetic acid

  • carboxyethylbenzene

  • 2-phenylpropanoic acid


317.

The correct order of acid strengths of benzoic acid (X), peroxybenzoic acid (Y) and p-nitrobenzoic acid (Z) is

  • Y > Z > X

  • Z > Y > X

  • Z > X > Y

  • Y > X > Z


318.

The structure of the product P of the following reaction is


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319.

Choose the correct statement(s) among the following.

  • CH3CHO on reaction with HCN gives racemic mixture 

  • CH3-CH=NOH shows geometrical isomerism


320.

Optical isomerism is exhibited by (ox= oxalate anion; en= ethylenediamine).

  • cis-[CrCl2(ox)2]3-

  • [Co(en)3]3+

  • trans-[CrCl2(ox)2]3-

  • [Co(ox)(en)2]+


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