Chemistry : Organic Chemistry – Some Basic Principles and Techniques

Acyclic stereoisomer having the molecular formula C₄H₇Cl are classified and tabulated. Find out the correct set of numbers

• Geometrical	optical
  6	2

• Geometrical	optical
  4	2

• Geometrical	optical
  6	0

• Geometrical	optical
  6	0

Compare List-I and List-II and choose the correct matching codes from the choices given.

List - I	List - II
A. Glycerol	i. Sublimation
B. o-nitrophenol	ii. Beilstein's test
C. Anthracene	iii. Victor- Meyer's method
D. Halogens	iv. Steam distillation
E. Molecular weight	v. Vaccum distillation vi. Eudiometry

• A - v; B - iv; C - i; D - ii; E - iii

• A - iv; B - v; C - i; D - vi; E - ii

• A - vi; B - iv; C - i; D - iii; E - ii

• A - v; B - iv; C - vi; D - ii; E - iii

Pick out the wrong statement.

• Toluene shows resonance

•  is non-aromatic

• The hybrid state of carbon in carbonyl group is sp² 

• The hyper-conjugative effect is known as no bond resonance

The number of isomers for the compound with the molecular formula C₂BrClFI is

• 3

• 4

• 5

• 6

Which among the following statements is correct with respect to the optical isomers?

• Enantiomers are non-superimposable mirror images

• Diastereomers are superimposable mirror images

• Enantiomers are superimposable mirror images

• Meso foms have no plane of symmetry

In Lassaigne's test, a blue colour is obtained if the organic compound contains nitrogen. The blue colour is due to

• K₄[Fe(CN)₆]

• Fe₄[Fe(CN)₆]₃

• Na₃[Fe(CN)₆]

• Cu₂[Fe(CN)₆]

Which of the following Fischer's projection formula is identical to D-glyceraldehyde?

A molecule of urea can show :

• chain isomerism

• position isomerism

• geometrical isomerism

• tautomerism

Which of the following compounds will exhibit cis-trans isomerism ?

• 2-butene

• 2-butyne

• 2-butanol

• Butanone

When 32.25 g of ethyl chloride is subjected to dehydrohalogenation reaction the yield of the alkene formed is 50%. The mass of the product formed is (atomic mass of chlorine is 35.5).

• 14 g

• 28 g

• 64.5 g

• 7 g