577.Give appropriate reason for the following observation: Fluorine is a stronger oxidising agent than chlorine, though fluorine has lower electron affinity than chlorine.
(i) Fluorine is small in size and have high electronegtivity than chlorine.
(ii)Fluorine has highest reduction potential due to higher hydraation energy of F– and Cl–.
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578.Give appropriate reason for the following observation: NO2 readily forms a dimer, whereas ClO2 does not.
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579.
Account for the following: Chlorine water has both oxidizing and bleaching properties.
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580.
Account for the following: H3PO2 and H3PO3 acts as good reducing agents while H3PO4 does not.