Which of the following is the correct method of preparation of me

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881.

Which of the following is the correct method of preparation of methyl fluoride?

  • CH4 + HF →

  • CH3OH + HF →

  • CH4 + F2

  • CH3Br + AgF →


D.

CH3Br + AgF →

Fluorination of hydrocarbons with pure F2 gas occurs explosively. Thus, alkyl fluorides are more conveniently prepared indirectly by heating suitable chloro or bromoalkanes with inorganic fluorides.

CH3Br + AgF →CH3F + AgBr

This reaction is known as Swarts reaction.


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882.

Which of the following species can function both as oxidising as well as reducing agent?

  • Cl-

  • ClO4-

  • ClO-

  • MnO4-


883.

Which of the following is used as an oxidiser in rocket propellants?

  • Ammonium perchlorate

  • Alcohol

  • Acrylic rubber

  • Polyurethane


884.

Concentrated sulphuric acid can be reduced by

  • NaCl

  • NaF

  • NaBr

  • NaOH


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885.

The element evolving two different gases on reaction with conc sulphuric acid is

  • P

  • C

  • Hg

  • S


886.

Which one of the following reactions will occur on heating AgNO3 above its melting point?

  • 2AgNO3 → 2Ag + 2NO2 + O2

  • 2AgNO3 → 2Ag + N2 + 3O2

  • 2AgNO3 → 2AgNO2 + O2

  • 2AgNO3 → 2Ag + 2NO + 2O2


887.

In alkaline medium ClO2, oxidises H2O2 to O2 and itself gets reduced to Cl. How many moles of H2O2 are oxidized by 1 mole of ClO2?

  • 1.0

  • 1.5

  • 2.5

  • 3.5


888.

The electron affinity values for the halogens show the following trend :

  • F < Cl > Br >I

  • F < Cl< Br< I

  • F > Cl > Br > I 

  • F < Cl > Br < I


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889.

When H2S gas is passed through nitric acid, the product is:

  • prismatic S (colloidal)

  • amorphous S

  • monoclinic S

  • plastic S


890.

Atoms in a P4 molecule of white phosphorus are arranged regularly in space in which of the following way ?

  • At the comers of tetrahedron

  • At the comers of a cube

  • At the comers of a four membered ring

  • At the centre and comers of a equivalent triangle


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