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 Multiple Choice QuestionsMultiple Choice Questions

291.

When 23 g sodium metal reacts with methyl alcohol , it will form :

  • 1 moles of H2

  • 2 mole of H2

  • 0.5 mole of H2

  • All of the above


292.

Which one of the following forms propanenitrile as the major product?

  • Propyl bromide + alcoholic KCN

  • Ethyl bromide + alcoholic KCN

  • Ethyl bromide + alcoholic AgCN

  • Propyl bromide + alcoholic AgCN


293.

The reaction


Can be classified as

  • Alcohol formation reaction

  • Dehydration reaction

  • Williamson alcohol synthesis reaction

  • Williamson alcohol synthesis reaction

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294.

The reaction,


is called,

  • Williamson synthesis

  • Williamson continuous etherification process

  • Etard reaction

  • Gattermam -Koch reaction


A.

Williamson synthesis

The reaction of alkyl halides with sodium alkoxide or sodium phenoxide to form ethers is called Williamson synthesis. Here, in this reaction alkyl halide should be primary and alkoxide e.g. should be bulkier as shown below,

R-X     +         R'-ONa       --->         R-O-R' + NaX
alkyl halide      sodium alkoxide          ether

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295.

Which of the following will not be soluble in sodium hydrogen carbonate ?

  • 2,4,6 trinitrophenol

  • Benzoic acid

  • o-nitrophenol

  • o-nitrophenol

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296.

Among the following sets of reactants which one produces anisole?

  • CH3CHO;RMgX

  • C6H5OH;NaOH; CH3I

  • C6H5OH;neutral FeCl3

  • C6H5OH;neutral FeCl3

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297.

Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated HI?

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298.

In the following reaction,

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299.

Which of the following compounds can be used as antifreeze in automobile radiators?

  • Methyl alcohol

  • Glycol

  • Nitrophenol

  • Nitrophenol

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300.

The reaction of phenol with chloroform in the presence of dilute sodium hydroxide finally introduces, which one of the following functional group? 

  • -CH2Cl

  • -COOH

  • -CHCl2

  • -CHCl2

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