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351.

P-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to form the compound B. The latter on acidic hydrolysis gives chiral carboxylic acid. The structure of the carboxylic acid is


352.

When acetone is treated with dilute alkali, the product obtained is

  • mesitylene

  • mesityl oxide

  • paraldehyde

  • phorone


353.

Hydride ion transfer takes place in

  • Frankland method

  • Wurtz reaction

  • Cannizaro's reaction

  • Wolff- Kishner reduction


354.

An organic compound C3H6O neither gives precipitate with semicarbazide nor reacts with sodium. It could be

  • CH3CH2CHO

  • CH3COCH3

  • CH2=CHCH2OH

  • CH2=CHOCH3


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355.

Lewisite, a chemical used inchemical warfare, is obtained from

  • phosphene

  • acetylene

  • ethylene

  • zinc phosphate


356.

Ketone upon treatment with Grignard reagents gives

  • primary alcohol

  • secondary alcohol

  • tertiary alcohol

  • aldehyde


357.

The reaction of sodium ethoxide with iodoethane to form diethyl etheris termed as

  • electrophilic substitution

  • nucleophilic substitution

  • electrophilic addition

  • radical substitution


358.

Which of the following compounds would be the main product of an aldol condensation of acetaldehyde and acetone ?

  • CH3CH=CHCHO

  • CH3CH=CHCOCH3

  • (CH3)2C= CHCHO

  • (CH3)2C= CHCOCH3


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359.

When benzaldehyde is treated with acetic anhydride, in the presence of corresponding salt of the acid, the product obtained is

  • cinnamic acid

  • cinnamaldehyde

  • crotonic acid

  • benzillic acid


360.

Cannizaro as well as aldol condensation reaction is given by

  • benzaldehyde

  • 2- methylpropanal

  • 2,2-dimethylpropanal

  • acetaldehyde


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