In the following reaction order, B isCH3CH2-COOH →P/Br2

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591.

The reagent used for the separation of acetaldehyde from acetophenone is

  • NaHSO3

  • C6H5NHNH2

  • NH2OH

  • NaOH-I2


592.

Among the following, the one which reacts most readily with ethanol is

  • p-nitrobenzyl bromide

  • p-chlorobenzyl bromide

  • p-methoxybenzyl bromide

  • p-methylbenzyl bromide.


593.

The nucleic acid base having two possible binding sites is

  • thymine

  • cytosine

  • guanine

  • adenine.


594.

o-Toluic acid on reaction with Br2+ Fe gives


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595.

The most suitable reagent for the conversion of

RCH2OH  RCHO is

  • KMnO4

  • K2Cr2O7

  • CrO3

  • PCC (pyridine chloro chromate).


596.

Assertion : Sucrose is a non-reducing sugar.

Reason : It has glycosidic linkage.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false


597.

Assertion : lsobutanal does not give iodofonn test.

Reason : It does not have α-hydrogen.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


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598.

In the following reaction order, B is

CH3CH2-COOH P/Br2 A H+alc.KOH B

  • CH2 =CH -COOH

  • CH2-CH(Br)-COOH

  • CH3CH2COBr

  • CH3CH2OH


A.

CH2 =CH -COOH

CH2-CH2-COOH P/Br2 CH3-CH(Br)-COOH H+alc.KOH CH2=CH-COOH +Br

P + Br2, is brominating agent that brominates the α-position. The product then undergo dehydrohalogenation in the presence of alcoholic potassium hydroxide.


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599.

The product of the given reaction is-


600.

Assertion : CH3OCH3 and C2H5OH has comparable molecular weight but boiling point of C2H5OH is more than dimethyl ether.

Reason : C2H5OH forms intermolecular Hbonding while CH3OCH3 forms intramolecular H-bonding.

  • If both Assertion and Reason are true and Reason is the correct explanation of Assertion.

  • If both Assertion and Reason are true but Reason is not the correct explanation of Assertion.

  • If Assertion is true but Reason is false.

  • If Assertion is false but Reason is true.


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