In Williamson's synthesis from Chemistry Aldehydes, Ketones and

Previous Year Papers

Download Solved Question Papers Free for Offline Practice and view Solutions Online.

Test Series

Take Zigya Full and Sectional Test Series. Time it out for real assessment and get your results instantly.

Test Yourself

Practice and master your preparation for a specific topic or chapter. Check you scores at the end of the test.
Advertisement

 Multiple Choice QuestionsMultiple Choice Questions

631.

When phenol is treated with CHCl3 and NaOH the product formed is

  • benzaldehyde

  • salicyaldehyde

  • salicylic acid

  • benzoic acid


632.

The Kolbe's electrolysis proceeds via

  • nucleophilic substitution mechanism

  • electrophilic addition mechanism

  • free radical mechanism

  • electrophilic substitution reaction


633.

Benedict's solution is not reduced by :

  • formaldehyde

  • acetaldehyde

  • glucose

  • acetic anhydride


634.

The reagent used in Gatterman Koch aldehyde synthesis is :-

  • Pb/ BaSO4

  • alkaline KMnO4

  • acidic KMnO4

  • CO + HCl


Advertisement
635.

Iodoform can be obtained on warming NaOH and iodine with

  • CH3-CH2-CH(OH)CH3

  • (CH3)2CH-CO-C2H5

  • CH3-CO-OCH3

  • (CH3)3CCH2OH


636.

Aldol condensation will not occur in :

  • HCHO

  • CH3CH2CHO

  • CH3COCH3

  • CH3CHO


637.

Ethers are isomeric with

  • aldehyde

  • ketones

  • both aldehyde and ketones

  • alcohols


Advertisement

638.

In Williamson's synthesis

  • an alkyl halide is treated with sodium alkoxide

  • an alkyl halide is treated with sodium

  • an alcohol is heated with cone. H2SO4  at 130°C

  • None of the above


A.

an alkyl halide is treated with sodium alkoxide

Williamson's synthesis - It is the best method for the laboratory preparation of both simple and mixed ethers and involves the action of sodium alkoxide on a suitable alkyl halide.

              C2H5-Br +C2H5ONa  C2H5-O-C2H5 +NaBrethybromide                           diethyl ether C2H5-Cl + C2H6ONa C2H6-O-C2H5+ NaCl                                                  ethyl phenyl ether


Advertisement
Advertisement
639.

The Cannizaro reaction is not given by

  • trimethyl acetaldehyde

  • acetaldehyde

  • benzaldehyde

  • formaldehyde


640.

Self condensation of acetaldehyde, in the presence of dilute alkalies gives

  • an acetal

  • an aldol

  • mesitylene

  • propionaldehyde


Advertisement