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141.

At a given temperature T, gases Ne, Ar, Xe and Kr are found to deviate from ideal gas behaviour. Their equation of state is given as p = RTV - b at T. Here, b is the van der Waals constant. Which gas will exhibit steepest increase in the plot of Z (compression factor) vs p?

  • Ne

  • Xe

  • Ar

  • Kr


142.

Consider the following table:

Gas a/(kPa dm6mol-1) b/(dm3mol-1)
A 642.32 0.05196
B 155.21 0.04136
C 431.91 0.05196
D 155.21 0.4382

And b are vander walls contants . The correct statement a Bout the gases is :

  • Gas A will occupy than gas D  Compressible than gas D Gas C will Occupy more volume than

  • gas A gas B will be more compressible than gas D Gas C will Occupy Lesser volume than

  • Gas A gas B will be more compressible than gas D Gas C will Occupy Lesser volume than

  • Gas A: gas B will be lesser Compressble than gas D


143.

Points I, II and III in the following plot respectively correspond to (Vmp: most probale velocity) 

 

  • Vmp of N2 (300K); Vmp of O2(400K); Vmp of H2 (300K)

  • Vmp of N2 (300K); Vmp of H2(300K); Vmp of O2 (400K)

  • Vmp of H2 (300K); Vmp of N2(300K); Vmp of O2 (400K)

  • Vmp of O2 (400K); Vmp of N2(400K); Vmp of H2 (300K)


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