In O2 and H2O2 , the O-O bond lengths are 1.21 and 1.48 Å respectively. In ozone, the average O-O bond length is
1.28 Å
1.18 Å
1.44 Å
1.52 Å
Among [Fe(H2O)6]+, [Fe(CN)6]3-, [Fe(Cl)6]3- species, the hybridisation state of the Fe atom are, respectively.
d2sp3, d2sp3, sp3d2
sp3d2,d2sp3, d2sp3
sp3d2, d2sp3,sp3d2
None of the above
Which of the following pair have identical bond order?
CN- and NO+
CN- and O
CN- and CN+
NO+ and O
Which one of the following statements is correct?
Ferromagnetic substance like ZnFe2O4 becomes paramagnetic on heating
NaCl is a paramagentic salt
CuSO4 is a diamagnetic salt
MnO is an example of antiferronmagnetic substance
The bonds present in the structure of dichromate ion are
four equivalent Cr-O bonds only
six equivalent Cr-O bonds and one Cr - O - O bond
six equivalent Cr-O bonds and one O-O bond
eight equivalent Cr-O bonds
The stablest radical among the following is
C6H5 - CH2 - H2
CH3H2
C6H5 - H2-CH3
CH3-H-CH3
C.
C6H5 - H2-CH3
The benzylic free radicals are more stable than alkyl free radicals because of the delocalisation of odd or unpaired electron on the benzene ring. Further, secondary free radical is more stable than primary free radical. Therefore, C6H5-H-CH3 is more stable than C6H5-CH2-H2.
Match List-I and List-II and choose the correct matching codes.
List - I | List - II |
A. [Ni(CN)4]2- | 1. Ti4+ |
B. CHlorophyll | 2. sp3; paramagentic |
C. Ziegler- Natta catalyst | 3. non-planar |
D. [NiCl4]2- | 4. Mg2+ |
E. Deoxyhaemoglobin |
5. Planar 6. dsp2; diamagentic |
A - 6; B - 4; C - 1; D - 2; E - 3
A - 2; B - 4; C - 1; D - 6; E - 3
A - 2; B - 4; C - 1; D - 6; E - 5
A - 6; B - 4; C - 1; D - 2; E - 5