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 Multiple Choice QuestionsMultiple Choice Questions

11.

Match List-I with List-II and choose the correct matching codes from the choices given.

List - I List - II
A. PCl5 1. Linear
B. IF7 2. Pyramidal
C. H3O+ 3. Trigonal bipyramidal
D. ClO2 4. Tetrahedral
E. NH4+

5. Pentagonal bipyramidal

6. Angular

  • A - 3; B - 5; C - 2; D - 1; E - 4

  • A - 3; B - 5; C - 4; D - 1; E - 2

  • A - 3; B - 5; C - 6; D - 1; E - 2

  • A - 3; B - 5; C - 2; D - 6; E - 4


12.

Among the following, the pair in which the two species are not isostructural are

  • IO3- and XeO3

  • PF6- and SF6

  • BH4- and NH4+

  • CO32- and NO2-


13.

Each B - H - B bridge in B2H6 is formed by the sharing of:

  • 2 electrons

  • 4 electrons

  • 1 electron

  • 3 electrons


14.

Which of the following overlaps leads to bonding?


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15.

In which of the following compound sp2 hybridisation is absent ?

  • CH ≡ C - CH = CH2

  • CH ≡ C - CH- CH3

  • CH- CH = CH2

  • CH= CH - CH- CH3


16.

What is the hybridization state of the central atom in the conjugate base of NH4+ ion?

  • sp

  • sp3

  • sp2

  • dsp2


17.

If the bond length and dipole moment of a diatomic molecule are 1.25 A and 1.0 D respectively, what is the percent ionic character of the bond ?

  • 10.66

  • 12.33

  • 16.66

  • 19.33


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18.

Which one of the following is a correct set ?

  • H2O, sp3, angular

  • BCl3, sp3, angular

  • NH4+, dsp2, square planar

  • CH4, dsp2, tetrahedral


A.

H2O, sp3, angular

Among the given pair of sets, set or option a is the correct one. They can be elaborated as-

Molecule bp + 1p Hybridisation  Shape
H2O 2 + 2 sp3 angular
BCl3 3 + 0 sp2 trigonal planar
NH4+ 4 + 0  sp3 Tetrahedral
CH4 4 + 0 sp3 Tetrahedral


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19.

Fluorine reacts with dilute NaOH and forms a gaseous product A. The bond angle in the molecule of A is

  • 104°40'

  • 103°

  • 107°

  • 109°28'


20.

The number of pπ-dπ 'pi' bonds present in XeO3 and XeO4 molecules, respectively are-

  • 3, 4

  • 4, 2

  • 2, 3

  • 3, 2


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