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 Multiple Choice QuestionsMultiple Choice Questions

1.

Which of the following statement about hydrogen is incorrect?

  • Hydrogen never acts as cation in ionic salts

  • Hydronium ion, H3O+ exist freely in solution

  • Dihydrogen does not act as a reducing agent

  • Dihydrogen does not act as a reducing agent

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2.

The reaction of aqueous KMnO4 with H2O2 in acidic conditions gives.

  • Mn4+ and O2

  • Mn2+ and O2

  • Mn2+ and O3

  • Mn2+ and O3


B.

Mn2+ and O2

The reaction of aqueous KMnO4 with H2O2 in acidic medium is 
3H2SO4 + KMnO4 +5 H2O2 --> 5O2 +2MnSO4 +8H2O +K2SO4

In the reaction, KMnO4 oxidise H2O2 to O2 and itself [MnO4-] gets reduced to Mn2+ ions as MnSO4. Hence, aqueous solution of KMnO4 with H2O2 yields Mn2+ and O2 in acidic conditions.

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3.

A hydrogen gas electrode is made by dipping platinum wire in a solution of HCl of pH =10 and by passing hydrogen gas through the platinum wire at 1 atm pressure. The oxidation potential of electrode would be

  • 0.0591 V

  • 0.59 V

  • 0.118 V

  • 0.118 V

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4.

Which one of the following molecular hydrides acts as a Lewis acid? 

  • NH3

  • H2O

  • B2H6

  • B2H6

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5.

Some statement about heavy water are given below

A) Heavy water is used as a moderator in nuclear reactors.

B) Heavy water is more associated than ordinary water.

C) Heavy water is more effective solvent than ordinary

  • A and B

  • A, B and C

  • B and C

  • B and C

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6.

In which case is a number of molecules of water maximum?

  • 18 mL of water

  • 0.18 g of water

  • 10-3 mol of water

  • 0.00224 L of water vapours at 1 atm and 273K


7.

Which one of the following reactions does not form gaseous product?

  • PbO2 + H2O2 

  • Acidified KMnO4 + H2O2 

  • PbS + H2O2 

  • Cl2 + H2O


8.

SF4 Hydrolysis X +YX + H2S Z

Here, Z is

  • SO3

  • colloidal sulphur

  • gaseous sulphur

  • solid sulphur


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9.

Which of the following atomic and physical properties of hydrogen is false?

  • Hydrogen > Deuterium > Tritium; (melting point/ K)

  • Hydrogen < Deuterium < Tritium; (boiling point/ K)

  • Hydrogen < Deuterium < Tritium; (density /gL-1)

  • Hydrogen > Deuterium > Tritium; (% relative abundance)


10.

When H2O2 is added to ice cold solution of acidified potassium dichromate in ether and the contents are shaken and allowed to stand

  • a blue colour is obtained in ether because of formation of CrO5

  • a blue colour is obtained in ether because of formation of CrO3

  • a blue colour is obtained in ether because of formation of Cr2(SO4)3

  • chromyl chloride is formed


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