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 Multiple Choice QuestionsMultiple Choice Questions

11.

In the reaction,

  • HgSO4/H2SO4

  • Cu2Cl2

  • H3PO2 and H2O

  • H3PO2 and H2O

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12.

Among the following compounds, the one that is most reactive towards electrophilic nitration is

  • Benzoic acid

  • Nitrobenzene

  • toluene

  • toluene

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13.

Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?

  • NaNH2

  • HCl

  • O2

  • O2

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14.

Consider the reaction,
RCHO +NH2NH2 →RCH =N-NH2
What sort of reaction is it?

  • Electrophilic addition elimination reaction

  • Free radical addition-elimination reaction

  • Electrophilic substitution elimination reaction

  • Electrophilic substitution elimination reaction

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15.

An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol and N2 gas was evolved. (A) on warming with CHCl3 and Caustic potash  gave  (C) which on reduction gave  iso-propyl methylamine predict the structure  of (A)

  • CH3-CH2 -NH -CH3

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16.

What is the product obtained in the following reaction?

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17.

Method by which aniline cannot be prepared is 

  • hydrolysis phenyl isocyanide with the acidic solution

  • degradation of benzamide with bromine in alkaline solution

  • reduction of nitrobenzene with H2/Pd in ethanol

  • reduction of nitrobenzene with H2/Pd in ethanol

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18.

Which of the following compound is most basic?

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19.

The following reaction, 


is known by the name

  • Friedel -Crafts reaction

  • Perkins reaction

  • Acetylation reaction

  • Acetylation reaction

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20.

Which of the following statements about primary amines is false?

  • Alkyl amine are stronger bases than aryl amines

  • Alkyl amines reacts with nitrous acid to produce alcohols

  • Aryl amines react with nitrous acid to produce phenols

  • Alkyl amines are stronger base than ammonia


C.

Aryl amines react with nitrous acid to produce phenols

i) The presence of electron withdrawing substituent decrease the basicity while the presence of electron releasing substituent like, -CH3 - C2H5 etc increases the acidity.

ii) HNO2 converts - NH2 group of an aliphatic amine into - OH while that of aromatic amines into - N =NCl.

Since phneyl group is a electron withdrawing group, it decreases the basicity. Alkyl group, on the other hand, being electron releasing, increases the basicity. Thus, alkyl amines are more basic as compared to arylamines as well as ammonia.

R-NH2 HNO2 R -OH
Thus, HNO2 (nitrous acid ) converts alkyl amines to alcohols. But,

C6H5NH2 HNO2 C6H5N = NClbenzene diazonium chloride

Thus, HNO2 does not convert aryl amines into phenol.


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