(i) Give the Clifford representation of constitution of bleaching powder.

(ii) Write the chemical reactions when bleaching powder reacts with dilute HCl.

(iii) What is responsible for its oxidizing as well as bleaching properties.

Complete the following reactions and name the type of reaction to which each belongs:

i) CH₃Br KOH (aq) --->
ii) H₂C=CH₂ +HCl --->

23.

(a) Write chemical equations for the following reactions and name the main product:  

(i) Formaldehyde with ammonia

(ii) Acetone with sodium hypoiodite

(iii) Oxalic acid with glycerol at 260°C.

(iv) Acetic anhydride with salicylic acid.

 An aromatic compound ‘A’ on analysis was found to contain C, 79.14% and H, 5.66%. When ‘A’ is treated with alkali it does not turn brown or become polymerized but reacts as follows :    

2A + NaOH = X + Y

(b)In excess of dil HCl, bleaching powder liberates Cl₂.
CaOCl₂ +2HCl --> CaCl₂ +H₂O +Cl₂

Where X = A + 2H; Y gives an acid, Z, on the addition of dilute HCl; here Z is Z = A + (O). Identify the compound ‘A’ and name the reaction it is undergoing by giving reasons in support of it.

What are the reaction products of the following ?  

(ii) Why are same compounds not obtained at the final stage ?

Give the monomers of the following polymers :

(i) Teflon    (ii) Bakelite

Name the type of isomerism exhibited by the following pairs of compounds : 

(i) Acetaldehyde and vinyl alcohol

(ii) Maleic acid and fumaric acid.