Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

Give the IUPAC name for

H3C-CH2-CO-H2C-CH2-CO-OCH3

  • ethyl-4-oxoheptanoate

  • methyl-4-oxoheptanoate

  • ethyl-4-oxohexanoate

  • methyl-4-oxohexanoate


32.

The catalyst used in Rosenmund reaction is :

  • Zn/ Hg

  • Pd / BaSO4

  • Raney Ni

  • Na in ethanol


33.

(CH2CO)2O + RMgX H2O?

  • ROOCH(CH2)COOR

  • RCOCH2CH2COCH

  • RCOOR

  • RCOOH


34.

The weakest acid amongst the following is :

  • ClCH2COOH

  • HCOOH

  • FCH2CH2COOH

  • CH2(I)COOH


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35.

Urea on slow heating gives :

  • NH2CONHNO2

  • NH2CONHCONH2

  • HCNO

  • NH2CONH2.HNO3


36.

Trans esterification is the process of :

  • conversion of an aliphatic acid to ester

  • conversion of an aromatic acid to ester

  • conversion of one ester to another ester

  • conversion of an ester into its components namely acid and alcohol


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37.

The correct sequence of base strengths in aqueous solution is :

  • (CH3)2NH > CH3NH2 > (CH3)3N

  • (CH3)3N > CH3NH>(CH3)2NH

  • (CH3)3N > CH3NH2 = (CH3)2NH

  • (CH3)2NH > (CH3)3N > CH3NH2 


A.

(CH3)2NH > CH3NH2 > (CH3)3N

The order of base strength of amines in aqueous solution is as:

          (CH3)2NH > CH3NH2 > (CH3)3N

Tertiary amine is less basic than primary and secondary amine due to steric effect of three methyl group present on nitrogen atom.

 


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38.

When aqueous solution of benzene diazoniumchloride is boiled, the product formed is:

  • C6H5CH2OH

  • C6H+ N2

  • C6H5COOH

  • C6H5OH


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39.

Carbylamine reaction is given by aliphatic :

  • primary amine

  • secondary amine

  • tertiary amine

  • quaternary ammonium salt


40.

C6H5CHO  NH3 ?

  • (C6H5CHN)2CH·C6H5

  • C6H5NHCH3

  • C6H5NHCH2

  • C6H5NHC6H5


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