Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

Which of the following is a ketohexose?

  • Glucose

  • Sucrose

  • Sucrose

  • Ribose


32.

Reaction of PCl3 and PhMgBr would give

  • bromobenzene

  • chlorobenzene

  • triphenylphosphine

  • dichlorobenzene


33.

Hydroboration oxidation of 4-methyl octene would give

  • 4-methyl octanol

  • 2-methyl decane

  • 4-methyl heptanol

  • 4-methyl-2-octanone


34.

When ethyl alcohol is heated with conc. H2SO4, the product obtained is

  • CH3COOC2H5

  • C2H2

  • C2H6

  • C2H4


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35.

Anisole is the product obtained from phenol by the reaction known as

  • coupling

  • etherification

  • oxidation

  • esterification


B.

etherification

In presence of NaOH or KOH, phenol reacts with alkyl halide and gives phenolic ether (C6H5OR).

C6H5OH + NaOH -H2O C6H5O- Na -NaXRX C6H5 -O-RVapour of C6H5OH  and CH3OH, with red hot ThO2(thoria) give anisole (phenolic ether).C6H5OH + CH3OH ThO2 C6H5OCH3 + H2O


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36.

Ethylene glycol gives oxalic acid on oxidation with

  • acidified K2Cr2O7

  • acidified KMnO4

  • alkaline KMnO4

  • periodic acid


37.

A Wittig reaction with an aldehyde gives

  • ketone compound

  • a long chain fatty acid

  • olefin compound

  • epoxide


38.

Cannizaro reaction is given by

  • HCHO

  • >C(OH)COOH

  • >CHCH2CHO

  • CH3CH2OH


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39.

Identify the reactant.

  • H2O

  • HCHO

  • CO

  • CH3CHO


40.

Maleic acid and fumaric acid are

  • position isomers

  • geometric isomers

  • enantiomers

  • functional isomers


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