Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

11.

The equivalent conductance at infinite dilution of a weak acid such as HF

  • can be determined by extrapolation of measurements on dilute solutions of HCl, HBr and HI

  • can be determined by measurement on very dilute HF solutions

  • can best be determined from measurements on dilute solutions of NaF, NaCl and HCl

  • is an undefined quantity


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12.

For a reaction of type A + B products, it is observed that doubling concentration of A causes the reaction rate to be four times as great, but doubling amount of B does not affect the rate. The unit of rate constant is

  • s-1

  • s-1 mol L-1

  • s-1 mol-1 L

  • s s-1 mol-2 L-2


C.

s-1 mol-1 L

Let the initial rate is R and order with respecy to A is x and B is y. Thus, rate law is,

rate, R = [A]x [B]y      .....(i)

On the doubling the concentration of A, the rate becomes 4R

4R= [2A]x [B]y      ....(ii)

On doubling concentration B, rate remains R,

R=[A]x [2B]yFrom equation (i) and (ii) we get R4R=12x122=12xx= 2From equation (i) and (iii), we get RR=12y 1=12yy= 0

Thus, actual rate law is, rate, R = [A]2 [B]0.The order of this reaction is 2 and for second order reaction units of rate constant are mol-1 Ls-1.


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13.

A chemical reaction was carried out at 320 K and 300 K. The rate constants were found to be k1 and k2 respectively. Then

  • k2= 4k1

  • k2 = 2k1

  • k2= 0.25 k1

  • k2=  0.5k1


14.

Across the lanthanide series, the basicity of the lanthanide hydroxides

  • increases

  • decreases

  • first increases and then decreases

  • first decreases and then increases


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15.

Frenkel defect is generally observed in

  • AgBr

  • Agl

  • ZnS

  • All of the above


16.

Most crystals show good cleavage because their atoms, ions or molecules are

  • weakly bonded together

  • strongly bonded together

  • spherically symmetrical

  • arranged in planes


17.

[Co(NH3)4Cl2]NO2 and [Co(NH3)4ClNO2]Cl exhibit whcih type of isomerism?

  • Geometrical

  • Optical

  • Linkage

  • Ionisation


18.
  1. Which of the following compounds is not coloured?
  • Na2[Cu(Cl)4]

  • Na[Cd(Cl)4]

  • K4[Fe(CN)6]

  • K3[Fe(CN)6]


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19.

Coordination number of Ni in [Ni(C2O4)3]4- is

  • 3

  • 6

  • 4

  • 5


20.

Sterling silver is

  • AgNO3

  • Ag2S

  • Alloy of 80% Ag+ 20% Cu

  • AgCl


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