Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

21.

The IUPAC name of the following compound,[(CH3)2CH—CH2—CH=CH—CH=CH(C2H5)—CH3] is

  • 2, 8-dimethyl-4, 6-decadiene

  • 1, 1, 7, 7-tetramethyl-2, 5-octadiene

  • 1, 5-diisopropyl-1, 4-hexadiene

  • 3, 9-dimethyl-4, 6-decadiene


22.

Chlorination of benzene in the presence of halogen carrier is an example of

  • aromatic nucleophilic substitution

  • aromatic electrophilic substitution

  • aromatic nucleophilic addition

  • aromatic electrophilic addition


23.

Aryl halides doesn't undergo nucleophilic substitution reactions under ordinary conditions because of

1. approach of nucleophile is retarded
2. carbon carrying halogen atoms is sp3-hybridised
3. the substrate molecule is destabilised due to resonance
4. partial double bond character between carbon and halogen

  • 2 and 4 only

  • 1 and 4 only

  • 2 and 3 only

  • 2, 3 and 4 only


24.

Which of the following undergoes reduction with hydrogen peroxide in alkaline medium?

  • Mn2+

  • FeO

  • PbS

  • HOCl


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25.

The metal that produces red-violet colour in the non-luminous flame is

  • Ba

  • Ag

  • Rb

  • Pb


26.

In Lassaigne's test for the detection of halogens, the sodium fusion extract is first boiled with concentrated nitric acid. This is

  • to remove silver halides

  • to decompose Na2S and NaCN, if present

  • to dissolve Ag2S

  • to dissolve AgCN, if formed


27.

In Lassaigne's test for the detection of halogens, the sodium fusion extract is first boiled with concentrated nitric acid. This is

  • to remove silver halides

  • to decompose Na2S and NaCN, if present

  • to dissolve Ag2S

  • to dissolve AgCN, if formed


28.

According to Ellingham diagram, the oxidation reaction of carbon to carbon monoxide may be used to reduce which one of the following oxides at the lowest temperature?

  • Al2O3

  • Cu2O

  • MgO

  • ZnO


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29.

Halogens exist in -1,+ 1, + 3, + 5 and 47 oxidation states. The halogen that exists only in -1 state is

  • F

  • Cl

  • Br

  • I


A.

F

Fluorine atom has no d-orbitals in its valence shell, therefore cannot expand its octet and thus, does not exhibit variable oxidation states. Being the most electronegative, it exhibits only -1 oxidation state.


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30.

Among the oxyacids of phosphorus, the dibasic acid is

  • H3PO3

  • H4P2O7

  • H2PO2

  • HPO3


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