Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

Which one ofthe following does not involve coagulation?

  • Formation of delta regions

  • Peptization

  • Treatment of drinking water by potash alum

  • Clotting of blood by the use of ferric chloride


32.

Which one of the following statements is true?

  • Saponification of oil yields a diol

  • Drying of oil involves hydrolysis

  • Addition of antioxidant to oil minimizes rancidity

  • Refining of oil involves hydrogenation


33.

The IUPAC name of K2[Ni(CN)4] is

  • potassium tetracyanonickelate (II)

  • potassium tetracyanatonickelate (III)

  • potassium tetracyanatonickel (II)

  • potassium tetracyanonickel (III)


34.

The spin only magnetic moment of Mn4+ ion is nearly

  • 3BM

  • 6BM

  • 4BM

  • 5BM


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35.

In Kjeldahl's method, ammonia from 5 g of food neutralizes 30 cm3 of 0.1 N acid. The percentage of nitrogen in the food is

  • 0.84

  • 8.4

  • 16.8

  • 1.68


36.

The activation energy for a reaction at the 37. temperature T K was found to be 2.303 RT J mo1-1. The ratio of the rate constant to Arrhenius factor is

  • 10-1

  • 10-2

  • 2 × 10-3

  • 2 × 10-2


37.

Time required for 100 per cent completion of a zero order reaction is

  • 2k/a

  • a/2k

  • a/k

  • ak


38.

Which one of the following is wrongly matched?

  • [Cu(NH3)4]2+  - Square planar

  • [Ni(CO)4]   - Netural ligand

  • [Fe(CN6)3-]  -  sp3d2

  • [Co(en)3]3+    - Follows EAN


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39.

9.65 C of electric current is passed through fused anhydrous magnesium chloride. The magnesium metal thus, obtained is completely converted into a Grignard reagent. The number of moles of the Grignard reagent obtained is

  • 5 × 10-4

  • 1 × 10-4

  • 5 × 10-5

  • 1 × 10-5


C.

5 × 10-5

MgCl2  Mg2+ + 2Cl-Mg2+  + 2e-  Mg (atcathode)                2F          1mol2F(2 × 96500 C) deposits Mg=1 mol9.65 C charges will deposite Mg = 1 × 9.652× 96500= 5 × 10-5 mol

In order to prepare Grignard reagent, one mole of Mg is used per mole of reagent obtained. Thus, by 5 x 10-5 mol Mg, 5 ×10-5 mole of Grignard reagent are obtained.


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40.

The standard emf of galvanic cell involving 3 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the reaction of the cell is

  • 1025

  • 1020

  • 1015

  • 1030


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