Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

11.

A radioactive atom YXM emits two a particles and one B particle successively. The number of neutrons in the nucleus of the product will be

  • X - 4 - Y

  • X - Y - 5

  • X - Y - 3

  • X - Y - 6


12.

Which one of the following is paramagnetic?

  • N2

  • NO

  • CO

  • O3


13.

The sp3d2 hybridisation of central atom of a molecule would lead to

  • square planar geometry

  • tetrahedral geometry

  • trigonal bipyramidal geometry

  • octahedral geometry


14.

Which of the following is used to prepare Cl2 gas at room temperature from concentrated HCl?

  • MnO2

  • H2S

  • KMnO4

  • Cr2O3


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15.

The normality of 30 volume H2O2 is

  • 2.678 N

  • 5.336 N

  • 8.034 N

  • 6.685 N


16.

A plot of ln K against 1T (abscissa) is expected to be a straight line with intercept on ordinate axis equal to

  • S°2.303 R

  • S°R

  • -S°R

  • R × S°


17.

The solubility of Ca3(PO4)2 in water is y mol/L. Its solubility product is

  • 6y4

  • 36y4

  • 64y5

  • 108y5


18.

Hybridisation of C2 and C3 of H3C-CH=C-CH3 are

  • sp, sp3

  • sp2, sp

  • sp2, sp2

  • sp, sp


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19.

The ease of nitration of the following three hydrocarbons follows the order 

  • II - III ≈ I

  • II > III > I

  • III > II > I

  • I = III > II


B.

II > III > I

The ease of nitration of the hydrocarbons depends upon the stability of arenium ion formed.

In compound II, the carbonium ion has two methyl groups capable of partially neutralising the positive charges on the ring carbon atoms.

In compound III, two methyl group has +I effect whereas in compound I, only one methyl group with +I effect is present. Thus, the stability of arenium ion and ease of nitration follows the order II > III > I.


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20.

Among the alkenes which one produces tertiary butyl alcohol on acid hydration? 

  • CH3-CH2-CH=CH2

  • CH3-CH=CH-CH3

  • (CH3)2C=CH2

  • CH3-CH=CH2


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