Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

41.

During the adsorption of krypton on activated charcoal at low temperature

  • H < 0 and S < 0

  • H > 0 and S < 0

  • H > 0 and S > 0

  • H < 0 and S > 0


42.

1 g of silver gets distributed between 10 cm3 of molten zinc and 100 cm3 of molten lead at 800°C. The percentage of silver still left in the lead layer is approximately

  • 2

  • 5

  • 3

  • 1


43.

In Ramsay and Rayleigh's isolation of noble gases from air, the nitrogen of the air is finally converted into

  • NaNO2 only

  • NO and NO2

  • NaNO3 only

  • NaNO2 and NaNO3


44.

The IUPAC name of the complex [Co(NH3)4Cl2]Cl is

  • dichloro tetraammine cobalt (III) chloride

  • tetraammine dichloro cobalt (III) chloride

  • tetraammine dichloro cobalt (II) chloride

  • tetraammine dichloro cobalt (IV) chloride


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45.

The time required for 100% completion of a zero order reaction is

  • ak

  • a2k

  • ak

  • 2ka


46.

E1, E2 and E3 are the emfs of the following three galvanic cells respectively.

(i) Zn (s) | Zn2+ (0.1 M) || Cu2+ (1M) | Cu (s)

(ii) Zn (s) | Zn2+ (1 M) || Cu2+ (1M) | Cu (s)

(iii) Zn (s) | Zn2+ (1 M) || Cu2+ (0.1M) | Cu (s)

Which one of the following is true?

  • E2 > E1 > E3

  • E1 > E2 > E3

  • E3 > E1 > E2

  • E3 > E2 > E1


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47.

The standard emf of a galvanic cell involving 2 moles of electrons in its redox reaction is 0.59 V. The equilibrium constant for the redox reaction of the cell is

  • 1020

  • 105

  • 10

  • 1010


A.

1020

In a galvanic cell, G° = -nFE°        ...(i)

Relationship between G° and equilibrium constant

G° = -2.303 RT log Kp                   ...(ii)

From equation (i) and (ii), we get

-2.303 RT log Kp = -nFE°

log Kp = nFE°2.303 RT = nE°2.303 RTF          = 2 × 0.590.059 = 20

Kp = AL (20)    (AL = Antilog)

    = 1020


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48.

9.65 C of electric current is passed through fused alyhdrous MgCl2. The magnesium metal thus obtained is completely converted into a Grignard reagent. The number of moles of Grignard reagent obtained is

  • 5 × 10-4

  • 1 × 10-4

  • 5 × 10-5

  • 1 × 10-5


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49.

Which one of the following does not involve coagulation?

  • Clotting of blood by the use of ferric chloride

  • Formation of delta region

  • Treatment of drinking water by potash alum

  • Peptization


50.

Asolution of two liquids boils at a temperature more than the boiling point of either of them. Hence, the binary solution shows

  • negative deviation from Raoult's law

  • positive deviation from Raoult's law

  • no deviation from Raoult's law

  • positive or negative deviation from Raoult's law depending upon the composition


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