When glycerol is treated with excess of HI, it produces
2-iodopropane
allyl iodide
propene
glycerol triiodide
Following compounds are given
(i) CH3CH2OH
(ii) CH3COCH3
(iii)
(iv) CH3OH
Which of the above compound(s) on being warmed with iodine solution and NaOH, will give iodoform?
(i), (iii) and (iv)
Only (ii)
(i), (ii) and (iii)
(i) and (ii)
Fructose reduces Tollen's reagent due to
asymmetric carbons
primary alcoholic group
secondary alcoholic group
enolisation of fructose followed by conversion to aldehyde by base
Which of the following is not a fat soluble vitamin?
Vitamin-B complex
Vitamin-D
Vitamin-E
Vitamin-A
Which of the statements about 'Denaturation' given below are correct?
Statements
(i) Denaturation of proteins causes loss of secondary and tertiary structures of the protein.
(ii) Denaturation leads to the conversion of double strand of DNA into single strand.
(iii) Denaturation affects primary structure which gets destroyed.
(ii) and (iii)
(i) and (iii)
(i) and (ii)
(i), (ii) and (iii)
The order of reactivity of phenyl magnesium bromide (PhMgBr) with the following compounds
III > II > I
II > I > III
I > III > II
I > II > III
D.
I > II > III
Since alkyl group has +I-effect and aryl group has +R-effect, thus greater the number of alkyl and aryl groups attached to the carbonyl group, its reactivity towards nucleophilic addition reaction. Secondly, as the steric crowding on carbonyl group increases, the reactivity decreases accordingly.
Therefor,correct reactivity order for reaction with PhMgBr is
Match the compounds given in List I with List II and select the suitable option using the codes given below.
List I | List II | ||
A. | Benzaldehyde | 1. | Phenolphthalein |
B. | Phthalic anhydride | 2. | Benzoin condensation |
C. | Phenyl benzoate | 3. | Oil of wintergreen |
D. | Methyl salicylate | 4. | Fries rearrangement |
A B C D
4 1 3 2
A B C D
4 2 3 1
A B C D
2 3 4 1
A B C D
2 1 4 3