Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

When glycerol is treated with excess of HI, it produces

  • 2-iodopropane

  • allyl iodide

  • propene

  • glycerol triiodide


32.

Which one of the following compounds will be most readily dehydrated?


33.

Following compounds are given

(i) CH3CH2OH

(ii) CH3COCH3

(iii) CH3-(CH)CHOH

(iv) CH3OH

Which of the above compound(s) on being warmed with iodine solution and NaOH, will give iodoform?

  • (i), (iii) and (iv)

  • Only (ii)

  • (i), (ii) and (iii)

  • (i) and (ii)


34.

Fructose reduces Tollen's reagent due to

  • asymmetric carbons

  • primary alcoholic group

  • secondary alcoholic group

  • enolisation of fructose followed by conversion to aldehyde by base


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35.

Which of the following is not a fat soluble vitamin?

  • Vitamin-B complex

  • Vitamin-D

  • Vitamin-E

  • Vitamin-A


36.

Which of the statements about 'Denaturation' given below are correct?
Statements

(i) Denaturation of proteins causes loss of secondary and tertiary structures of the protein.
(ii) Denaturation leads to the conversion of double strand of DNA into single strand.
(iii) Denaturation affects primary structure which gets destroyed.

  • (ii) and (iii)

  • (i) and (iii)

  • (i) and (ii)

  • (i), (ii) and (iii)


37.

In the following reaction,

             C6H5CH2Br (ii)H3O+(i) Mg, EtherX, the product 'X' is

  • C6H5CH2OCH2C6H5

  • C6H5CH2OH

  • C6H5CH3

  • C6H5CH2CH2C6H5


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38.

The order of reactivity of phenyl magnesium bromide (PhMgBr) with the following compounds

  • III > II > I

  • II > I > III

  • I > III > II

  • I > II > III


D.

I > II > III

Since alkyl group has +I-effect and aryl group has +R-effect, thus greater the number of alkyl and aryl groups attached to the carbonyl group, its reactivity towards nucleophilic addition reaction. Secondly, as the steric crowding on carbonyl group increases, the reactivity decreases accordingly.
Therefor,correct reactivity order for reaction with PhMgBr is

                


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39.

Match the compounds given in List I with List II and select the suitable option using the codes given below.

  List I   List II
A. Benzaldehyde 1. Phenolphthalein
B. Phthalic anhydride 2. Benzoin
condensation
C. Phenyl benzoate 3. Oil of wintergreen
D. Methyl salicylate 4. Fries rearrangement

  • A   B   C   D

    4   1   3   2

  • A   B   C   D

    4   2   3    1

  • A   B   C   D

    2   3   4   1

  • A   B   C   D

    2   1   4    3


40.

Which of the following compound is the most basic?


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