The emf of a galvanic cell constituted with the electrode Zn2+|Zn

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

41.

excess of PCl5 reacts with concentrated H2SO4 giving

  • chlorosulphuric acid

  • sulphurous acid

  • sulphury chloride

  • thionyl chloride


42.

Which one of the following shows highest magnetic moment?

  • Fe2+

  • Co2+

  • Cr3+

  • Ni2+


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43.

The emf of a galvanic cell constituted with the electrode Zn2+|Zn (-0.76V) and Fe2+|Fe (-0.41V) is

  • -0.35V

  • + 1.17V

  • +0.35V

  • -1.17V


C.

+0.35V

The cell reaction may be split two half reactions as 

Zn2+ + 2e- → Zn, Ered°= -0.76V

Fe2+ + 2e- → Fe,  Ered°= -0.44V
As Zn2+ ion has lower reduction potential than Fe2+ ion. Thus, oxidation takes place on zinc electrode standard EMF of the cell.

 =[Standard reduction potential of the reduction half reaction]-[Standard reduction potential of the oxidation half reaction]

= -0.44-(-0.76)

=+ 0.035V

 


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44.

Which of the following is not a colligative property?

  • Elevation in boiling point

  • Depression in freezing point

  • Osmotic pressure

  • Lowering of vapour pressure


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45.

3 g of urea is dissolved in 45 g of H2O. The relative lowering in vapour pressure is

  • 0.05

  • 0.04

  • 0.02

  • 0.01


46.

Metallic lustre is due to

  • high density of metals

  • high polish on the surface of metals

  • reflection of light by mobile electrons

  • chemical inertness of metals


47.

Which of the following aqueous solution will exhibit highest boiling point?

  • 0.01M urea

  • 0.01 M KNO3

  • 0.01M Na2SO4

  • 0.015M C6H12O6


48.

Glucose when reduced with HI and red phosphorus gives

  • n-hexane

  • n-heptane

  • n-pentane

  • n-octane


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49.

Oils are liquids at room temperature since they contain higher percentage of

  • oleates

  • palmitates

  • stearates

  • myristates


50.

The number of disulphide linkages present in insulin are

  • 4

  • 3

  • 2

  • 1


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