excess of PCl5 reacts with concentrated H2SO4 giving
chlorosulphuric acid
sulphurous acid
sulphury chloride
thionyl chloride
The emf of a galvanic cell constituted with the electrode Zn2+|Zn (-0.76V) and Fe2+|Fe (-0.41V) is
-0.35V
+ 1.17V
+0.35V
-1.17V
C.
+0.35V
The cell reaction may be split two half reactions as
Zn2+ + 2e- → Zn, E= -0.76V
Fe2+ + 2e- → Fe, E= -0.44V
As Zn2+ ion has lower reduction potential than Fe2+ ion. Thus, oxidation takes place on zinc electrode standard EMF of the cell.
=[Standard reduction potential of the reduction half reaction]-[Standard reduction potential of the oxidation half reaction]
= -0.44-(-0.76)
=+ 0.035V
Which of the following is not a colligative property?
Elevation in boiling point
Depression in freezing point
Osmotic pressure
Lowering of vapour pressure
3 g of urea is dissolved in 45 g of H2O. The relative lowering in vapour pressure is
0.05
0.04
0.02
0.01
Metallic lustre is due to
high density of metals
high polish on the surface of metals
reflection of light by mobile electrons
chemical inertness of metals
Which of the following aqueous solution will exhibit highest boiling point?
0.01M urea
0.01 M KNO3
0.01M Na2SO4
0.015M C6H12O6
Oils are liquids at room temperature since they contain higher percentage of
oleates
palmitates
stearates
myristates