Which of the following is the strongest nucleophile?
OH-
CH3O-
CH3S-
C2H5O-
D.
C2H5O-
In (a), (b) and (d) nucleophilic site is same, so nucleophilicity follows the same order as basicity. The order of acidic character of conjugate acid of these bases is:
C2H5OH < H2O< CH3OH
So, the order of basicIty of their base is of opposite order:
C2H5O- > OH- > CH3O-
Between (b) and (c), CH3 is more nucleophihc as S is less electronegative as compared to O.So, the order of nucleophilicity is:
C2H5O- > OH- >CH > CH3O-
The incorrect statements among the following is
the first ionisation potential of Al is less than the first ionisation potential of Mg
the second ionsiation potential of Mg is lower than the second ionsiation potential of Na
the first ionisation potential of Na is less than the first ionisation potential of Mg
the third ionisation potential of Mg is greater than the third ionisation potential of Al
When the sample of copper with zinc impurity is to be purified by electrolysis, the appropriate electrodes are
Anode | Cathode |
Pure zinc | pure copper |
Anode | Cathode |
impure zinc | pure copper |
Anode | Cathode |
impure zinc | impure sample |
Anode | Cathode |
impure sample | pure copper |
Which one of the following arrangements represents the correct order of electron gain enthalpy (with negative sign) of the given atomic species?
Cl <F <S <CO
O <S <F <Cl
S <O <Cl <F
F <Cl <O <S
Acidified solution of chromic acid on treatment with H2O2 yields
CrO3 + H2O + O2
Cr2O3 + H2O + O2
CrO5 + H2O
H2Cr2O7 + H2O + O2
Which of the following is an alum?
Na·AlO2
Na2SO4·Al2(SO4)3·24H2O
KCl·MgCl2·6H2O
FeSO4 ·(NH4)2SO4·6H2O