36 g water and 828 g ethyl alcohol form an ideal solution. The mole fraction of water in it, is :
1.0
0.7
0.4
0.1
D.
0.1
Number of moles of water (n) = = 2
No. of moles of ethyl alcohol (N) = = 18
Mole-fraction of water =
= = = 0.1
PCl5 was heated in a 10 dm3 container at 250°C
PCl5(g) PCl3(g) + Cl2 (g)
0.1 mol PCl5 and 0.2 mol Cl2 was found at equilibrium. The equilibrium constant for the reaction is :
0.025
0.04
0.02
0.05
B.
0.04
PCl5 PCl3 + Cl2
a 0 0
(a-x) 0.2 0.2(in equil)
0.1 mol mol mol
Hence, Kc = =
= 0.04
In the reaction,
H2SO4 + H2O H3O+ + HSO4-,
the conjugate acid of water is :
H3O+
H2O
HSO4-
SO42-
A.
H3O+
The conjugate acid of water is H3O+
What will be the main product, when benzene vapours are passed over V2O5 at 450°C ?
B.
Maleic anhydride is obtained by the oxidation of benzene in the presence of V2O5 at 450°C .
2C6H6 + 9O2 ( maleic anhydride) + 4H2O +CO2
Poisonous gas 'Lewisite' is obtained by the reaction of :
CHCH and AsCl3
CH2=CH2 and AsCl3
CHCH and S2Cl2
CH2=CH2 and NOCl
A.
CHCH and AsCl3
Poisonous gas 'Lewisite' is obtained by the reaction of AsCl3 with acetylene
CHCH + AsCl3
Hydrogen in respect to chlorine, is :
electropositive
electronegative
neutral
none of the above
B.
electronegative
Chlorine is more electronegative (electronegativity = 3.0) than hydrogen (2.1). Hence, hydrogen is electropositive in respect to chlorine.
Which of the follownig elements, is most electronegative ?
F
O
Ne
Na
A.
F
Fluorine is the most electronegative element of the periodic table. Its electronegativity is 4.0.
What is obtained , when propene is treated with N-bromo succinimide ?
CH3-CBr=CH2
BrCH2-CH=CH2
BrCH2-CH=CHBr
BrCH2-CHBr-CH2Br
B.
BrCH2-CH=CH2
Propene reacts with N-bromo succinimide to give allyl bromide , as the allyl hydrogen is comparitively easier to be replaced than vinyl hydrogen .
Phenolphthalein is not suitable for the titration of :
NaOH vs (COOH)2
KOH vs H2SO4
K2CO3 vs HCl
none of the above
C.
K2CO3 vs HCl
Phenolphthalein indicator is suitable for the titration of strong base vs. strong acid and strong base vs. weak acid. Here, NaOH, KOH are strong bases and K2CO3 also give strong base (KOH) in solution. Hence, phenolphthalien is suitable for each titration.
For a gaseous reaction,
C2H4 + H2 C2H6 ; H = -32.7 Kcal.
The concentration of C2H4 can be decreased by :
increasing pressure
increasing amount of H2
decreasing temperature
all of these
D.
all of these
C2H4 + H2 C2H6 + 32.7 Kcal
In this reaction, volume is decreasing and heat is evolving. Hence, according to Le-Chatelier principle, we have to increase pressure, decrease temperature and increase concentration of H2 to make the reaction proceed in forward direction.