The number of moles of oxygen obtained by the electrolytic decomposition of 108 g water is
2.5
3
5
7.5
B.
3
2H2O 2H2 + O2
2mol 1mol
2 x 18 = 36 gm
Since, 36 gm of H2O produce 1 mole of oxygen.
108 gm of water will produce oxygen = = 3 mol
The pH of a 0.001 M solution of HCl is
0
3
5
10
B.
3
pH of 0.001 M solution of HCl is 3.
[H+] = 0.001
pH = -log [H+]
= -log [10-3]
= 3
A fruity smell is produced by the reaction of C2H5OH with
CH3COCH3
CH3COOH
PCl5
CH3CHO
B.
CH3COOH
C2H5OH reacts with CH3COOH and gives ethylethanoate. It is an ester and has fruity smell.
C2H5OH + CH3COOH CH3COOC2H5 + H2O
Ester
The set representing the correct order for first ionisation potential is
K > Na > Li
Be > Mg > Ca
B > C > N
Ge > Si > C
A.
K > Na > Li
The ionisation potential decreses in group on moving downward because atomic radius increases hence, the correct order is
Be > Mg > Ca
Bleaching powder is obtained by treating Cl2 with
Ca(OH)2
CaO
CaCO3
CaCl2
A.
Ca(OH)2
Bleaching powder is obtained by treating Cl2 with lime water.
Ca(OH)2 + Cl2 CaOCl2 + H2O
The hybridisation state of carbon in fullerene is
sp
sp2
sp3
sp3d
B.
sp2
The hybridisation state of carbon in fullerene is sp2.
Solubility product of PbCl2 at 298 K is 1 x 10-6. At this temperature solubility of PbCl2 in mol/L is
(1 x 10-6)1/2
(1 x 10-6)1/3
(0.25 x 10-6)1/3
(2.5 x 10-6)1/2
C.
(0.25 x 10-6)1/3
KSP = (S) (2S)2
1 x 10-6 = 4S3
S = = (0.25 x 10-6)1/3
Therefore, temperature solubility of PbCl2 in mol/L is (0.25 x 10-6)1/3
Plaster of paris is
CaSO4.H2O
CaSO4.2H2O
CaSO4.H2O
CaSO4.4H2O
A.
CaSO4.H2O
Calcium sulphate hemihydrate (CaSO4.H2O) is called plaster of paris.
When dihydroxy acetone reacts with HIO4, the product is/ are
HCHO
HCOOH
HCHO and HCOOH
HCHO and CO2
D.
HCHO and CO2
When dihydroxy acetone reacts with HIO4, products formed are HCHO and CO2.
Heavy water is
CaSO4
water contain CaSO4, MgSO4
D2O
water contain CaCO3
C.
D2O
D2O is called heavy water. It is used as moderator in nuclear reactor.