Subject

Chemistry

Class

NEET Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

Which one of the following gives, on ozonolysis, both aldehydes and ketones?

  • Me2C = CHMe

  • Me2C = CMe2

  • MeCH2 - C(Me) = CMe2

  • MeCH(Me) - CH = CHMe


32.

Benzoylation of phenol in alkaline medium is known as

  • Friedel-Craft's reaction

  • Wurtz-Fittig reaction

  • Schotten-Baumann reaction

  • Sabatier Senderens reduction


33.

Which one of the following compounds is most reactive towards nucleophilic addition?

  • CH3CHO

  • PhCOCH3

  • PhCOPh

  • CH3COCH3


34.

Distillation of acetone with concentrated sulphuric acid gives

  • diacetone alcohol

  • mesityl oxide

  • mesitylene 

  • propene-2-ol


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35.

RCH2CH2OH can be converted to RCH2CH2COOH by the following sequence of steps

  • PBr3, KCN , H3O+

  • PBr3, KCN, H2/P+

  • KCN, H3O+

  • HCN, PBr3, H3O+


36.

Formation of cyanohydrin from a ketone is an example of

  • electrophilic addition

  • nucleophilic substitution

  • nucleophilic addition

  • electrophilic substitution


37.

How many primary amines are possible with the formula C4H11N?

  • 1

  • 2

  • 3

  • 4


38.

Which of the following will produce only one product on reduction with LiAlH4?

  • CH3OCOCH2CH3

  • CH3CH2OCOCH2CH3

  • CH3CH2OCOCH3

  • CH3CH2OCOCH2CH2CH3


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39.

Which one of the following pairs gives effervescence with aqueous NaHCO3?

I. CH3COCl

II. CH3COCH3

III. CH3COOCH3

IV. CH3COOCOCH3

  • I and III

  • I and IV

  • II and III

  • I and III


B.

I and IV

Due to strong negative inductive effect shown by -Cl and -OCOCH3 group, acid chloride and acid anhydride are highly reactive among acid derivatives. They react independently with water even in the absence of catalyst to give carboxylic acid.

CH3COCl NaHCO3 (aq) CH3COONa + CO2 + HCl

CH3COOCOCH3 NaHCO3 (aq.) 2CH3COONa + CO2


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40.

A tripeptide is written as glycine-alanine -glycine. The correct structure of the tripeptide is


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