The function of Fe(OH)3 in the contact process is :
to remove arsenic impurity
to detect colloidal impurity
to detect colloidal impurity
to remove dust particles
Consider the following statements :
I. Increase in concentration of reactant increases the rate of a zero order reaction
II. Rate constant k is equal to collision frequency A , if Ea =0
III. Rate constant k is equal to collision
frequency A , if Ea = ∞
IV. ln k vs T is a straight line
V. ln k vs 1/T is a straight line
Correct statements are :
I and IV
II and V
III and IV
II and III
Which of the following isomeric heptanes can yield seven different monochlorinated products upon free radical chlorination?
3-methyl hexane
2, 2-dimethyl pentane
2-methyl hexane
2, 3-dimethyl pentane
The compound which is not formed during the dry distillation of a mixture of calcium formate and calcium acetate is :
methanal
propanal
propanone
ethanal
Arrange the following in the increasing order of their basic strengths :
CH3NH2 , (CH3)2NH , (CH3)3N , NH3
NH3 < (CH3)3N < (CH3)2NH < CH3NH2
NH3 < (CH3)3N < CH3NH2 < (CH3)2NH
(CH3)3N < NH3 < CH3NH2 < (CH3)2NH
CH3NH2 < (CH3)2NH < (CH3)3N < NH3
B.
NH3 < (CH3)3N < CH3NH2 < (CH3)2NH
Aliphatic amines are more basic than NH3 due to + I effect of alkyl groups. In aqueous medium, tertiary amine is less basic than secondary amine, because the cation formed by protonation of tertiary amine is less solvated as compared to the cation formed by protonation of secondary amine. Hence, the increasing order of the basic strength is as ,
NH3 < (CH3)3N < CH3NH2 < (CH3)2NH
What is the correct order of acidity from weakest to strongest acid for these compounds :
I < IV < III < II
III < IV < III < II
IV < I < III < II
II < III < I < IV
The correct order of reactivity of the three halides ethyl chloride (I), iso-propyl chloride (II) and benzyl chloride (III) in SN1 reaction is :
I > II > III
III > II >I
II > I > III
I > III > II