[NiCl]42- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why? - Zigya
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[NiCl]42- is paramagnetic while [Ni(CO)4] is diamagnetic though both are tetrahedral. Why?


In Ni(CO)4, Ni is the zero oxidation state whereas in NiCl42–, it is in +2 oxidation state. In the presence of CO ligand, which is strong ligand can paired all electron in Ni(CO), Hence it is a diamagentic in nature. But Cl being a weak ligand is unable to pair up the unpaired electrons. Hence NiCl42- is paramagnetic in nature.
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