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When hydrochloric acid is added to marble pieces, a gas (A) is evolved. On passing gas A through lime water, a white precipitate of (B) is formed. When excess of A is passed, B dissolves due to the formation of soluble C. Identify A, B and C. Explain the reactions.


Chemical Reactions:
Marble is calcium carbonate. It reacts with HCl to give CO2
CaCO3 + 2HCl                          CaCl+ CO2 + H2O
Marble                                             (A)

CO2 when passed through lime water [Ca(OH)2] gives a white precipitate of CaCO3.
Ca(OH)+ CO2(g)                    CaCO3(s) + H2O
                                             White ppt.
                                                  (B)
On passing excess CO2, CaCO3 dissolves forming soluble Ca(HCO3)2.
CaCO+ CO+H2O Ca(HCO3)2 (aq)
                                   Calcium
                                   hydrogen
                                   carbonate
                                       (C)

A — Carbon dioxide
B — Calcium carbonate
C — Calcium hydrogen carbonate
                                   

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