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Why does hydrogen occur in a diatomic form rather than in a monoatomic form under normal conditions?


A molecule of hydrogen is formed by the combination of two atoms of hydrogen with one electron each present in the 1s orbital. hydrogen (1s1) has one electron less than the stable inert gas configuration (He;1s2) and therefore it shares its single electron with an electron of another hydrogen atom to form a stable diatomic molecule. Thus two electrons are present in the hydrogen molecule and both will be accommodated in the molecular orbital of lowest energy. The bond order of H2 is +1. The positive value of bond order indicates that the H2 (diatomic) molecules are stable.


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Write the names of isotopes of hydrogen. What is the mass ratio of these isotopes? 

Name of isotopes of hydrogen:


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Describe the bulk preparation of hydrogen by an electrolytic method. What is the role of electrolyte in this process?
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How is dihydrogen manufactured by the electrolysis of water?


It is manufactured by the electrolysis of water containing a small amount of acid or alkali(electrolyte) using nickel plated iron as anode and iron as a cathode. The two electrodes are separated from each other by an asbestos diaphragm which prevents mixing of H2 and O2. On passing an electric current, water is decomposed into hydrogen and oxygen. Dihydrogen is collected at the cathode while oxygen is collected at the anode.

        
The role of electrolyte (acid) is to make water conducting. 

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How can the production of dihydrogen, obtained from 'coal gasification' be increased?


Coal gasification is the process of producing syngas or synthesis gas (water gas) from coal.



The production of dihydrogen can be increased by passing carbon monoxide gas(of syngas) through steam in the presence of iron chromate (catalyst) at 673 K.


The COso produced is removed by scrubbing with a solution of sodium arsenite.
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Justify the position of hydrogen in the periodic table on the basis of its electronic configuration.

Hydrogen (Z=1) has electronic configuration 1s1. On one hand, its electronic configuration is similar to the outer electronic configuration (ns1) of alkali metals.


On the other hand, like halogens (having electronic configuration ns2np5 belonging to group 17 of the periodic table), it is short by one electron to the corresponding noble gas configuration (ns2np6).
                       

Although hydrogen to a certain extent resembles both with alkali metals (Group I) and halogens (Group 17), yet it differs from them as well. Therefore, it is best placed separately in the periodic table.
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